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  • 1
    Publication Date: 2017-04-04
    Description: Mud volcanoes represent the largest expression of natural methane release into the atmosphere; however, the gas flux has never been investigated in detail. Methane output from vents and diffuse soil degassing is herewith reported for the first time. Measurements were carried out at 5 mud volcano fields around Sicily (Italy). Each mud volcano is characterized by tens of vents and bubbling pools. In the quiescent phase, methane emission from single vents ranges between 0.01 and 6.8 kg/day. Diffuse soil leakage around the vents is in the order of 102–104 mg m 2 d 1. An exceptional flux of 106 mg m 2 d 1 was recorded close to an everlasting fire. Soil CH4 flux is positive even at large distances from the mud volcano fields suggesting a diffuse microseepage over wider areas. A total of at least 400 tons CH4 per year can be estimated over the area investigated alone ( 1.5 km2).
    Description: Published
    Description: 1215
    Description: partially_open
    Keywords: methane ; flux measurements ; Sicily ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 503 bytes
    Format: 151114 bytes
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  • 2
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    American Geophysical Union
    In:  Etiope G., Caracausi A., Favara R., Italiano F., Baciu C. (2002) Methane emission from the mud volcanoes of Sicily (Italy). Geoph. Res. Letters 29, 14340-14343.
    Publication Date: 2017-04-04
    Description: The paper ‘‘Methane emission from the mud volcanoes of Sicily (Italy)’’ by Etiope et al. [2002] represents the first report ever done on experimental CH4 output data from subaerial mud volcanoes (MV). A review of available CH4 flux data and detailed discussion about the global implications of mud volcanic CH4 emission has been made elsewhere [Etiope and Klusman, 2002; Morner and Etiope, 2002]. [2] The comment by Kopf [2003] contributes to open discussions and to make the readership aware on how important this subject is. In this reply we wish to clarify that precise data of CH4 flux from geologic sources are beginning to be available only now. It would be opportune that the MV-expert community could agree in using a common unit for the gas flux. We propose t y 1 and Mt y 1, and not metres cubed, consistently with the data reported for the methane sources/sinks budget by the IPCC. [3] Sicilian MVs, the first to be measured in detail, are considerably much smaller than the Azeri Ashgil MV, mentioned by Kopf [2003], and it is therefore obvious to expect a lower gas flux. Anyway the Dashgil mud volcano flux data are not based on exact measurements but only on visual estimates of the bubbles [Hovland et al., 1997]. In order to fully reply to Kopf [2003], hereafter we briefly discuss the problem of how to estimate the total number of MVs in the world and present new data from other European MVs, recently investigated. Finally, we outline the global importance of mud volcanic CH4 emission, as Kopf [2003] and recent literature is stressing.
    Description: Published
    Description: 1094
    Description: partially_open
    Keywords: methane ; mud volcanoes ; helium ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 02. Cryosphere::02.03. Ice cores::02.03.02. Atmospheric Chemistry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 503 bytes
    Format: 192711 bytes
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  • 3
    Publication Date: 2017-04-04
    Description: As shown by previously performed flux measurements, the mud volcanoes of Berca-Arbănaşi hydrocarbon-bearing structure in Eastern Carpathians Foredeep, including Pâclele Mari, Pâclele Mici, and Fierbători, represent a main gas seepage system in Romania, with considerable emissions of methane. The present work completes these gas emission studies by reporting the flux of methane and carbon dioxide at Beciu mud volcano, belonging to the same structure, not measured previously. In total, 78 measurements were carried out in June 2011 (40 on the vents, 34 on the area covered by mud and 4 in the external area, covered by vegetation). Diffuse fluxes from mud were found ranging from 102 to 105 mg CH4 m-2 day-1, and 102-104 mg CO2 m-2 day-1; the emission from individual vents was in the range of 0.014 to 32 t CH4 year-1 and 0.003 to 2.9 t CO2 year-1. These values are comparable with those typically documented for mud volcanoes worldwide. Gas seepage occurs pervasively throughout the muddy cover, even if it appears to be saturated with water. The total emission of CH4 and CO2 from Beciu mud volcano is conservatively estimated to be at least 190 t year-1 and 35 t year-1, respectively. The Beciu output leads the total CH4 emission from the four Berca mud volcanoes to at least 1350 t year-1, a value comparable with that reported for a similar number of giant mud volcanoes in Azerbaijan. This work contributed to update the geogenic gas flux data-set of Romania and to extend the global data-set of methane and carbon dioxide emissions from mud volcanoes.
    Description: Published
    Description: 159 - 166
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: mud volcanoes ; greenhouse gas emissions ; methane ; carbon dioxide ; gas flux ; soil degassing ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2019-11-04
    Description: Romania is one of the European countries with the most vigorous natural seepage of methane, uprising from pressurised natural gas and petroleum reservoirs through deep faults. The largest seepage zone is represented by large mud volcanoes, with CH4 〉80% v/v, occurring on the Berca-Arbanasi hydrocarbon-bearing faulted anticline, in the Carpathian Foredeep. Smaller mud volcanoes have been identified in other areas of the Carpathian Foredeep, in the Transylvanian Depression and on the Moldavian Platform. New surveys carried out in Transylvania allowed us to discover the richest N2 mud volcano zone in the world (N2〉90% v/v), with a remarkably high He content and a helium isotopic signature which highlights a contribution of mantle-derived source. The large mud volcanoes are generally quiescent, with rare explosive episodes and provide a methane flux in the order of 102-103 t km−2 y−1. Independently from mud volcanism, a remarkable dry macroseepage, however, has been found, with a degassing rate up to three orders of magnitude higher than that of mud volcanoes (i.e. 103-105 t km−2 y−1). The total gas flux from all investigated macroseepage zones in Romania is estimated in the range of 1500-2500 t y−1. The emission from microseepage, pervasively occurring throughout the hydrocarbon-prone basins, has yet to be assessed and added to the total gas output to the atmosphere.
    Description: Published
    Description: 501-512
    Description: 3.2. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: methane ; mud volcanoes ; Romania ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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