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  • 1
    ISSN: 1612-1112
    Keywords: Trace organics ; Aqueous solutions ; Concentration ; Thermal desorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A novel technique for the analysis of volatile trace organics in aqueous solutions has been developed. Concentration of organics is performed by passage of the solution being analysed through uncoated hydrophobic capillaries as previously reported. The concentrated organics are then thermally desorbed into a cold trap and subsequently analysed by gas chromatography. The water vapor being coeluted during desorption is selectively removed by the use of a membrane dryer. Quantitative analysis of trace organics in aqueous samples has been successfully carried out in this manner.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1612-1112
    Keywords: Concentration effects ; Uncoated capillary columns ; Trace organics ; Large aqueous volumes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A new technique has been developed for the concentration of organics in aqueous solutions. Volumes greater than 100 ml can be utilized in this system, which previously could not have been done without a distillation or solvent extraction procedure. The method is based on the passage of the solution through uncoated capillary columns of various materials such as polyethylene, copper, aluminum, nickel, and many other metal and/or polymer columns of different dimensions. It is possible to achieve trace level analysis at the ppb to ppt level without the interferences inherent in other existing methods. The purification of solvents has been successfully demonstrated in this preliminary study, and will be discussed along with our suggestions for future investigations.
    Type of Medium: Electronic Resource
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