ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The first direct determination of a 1,2-chlorine atom shift in a chlorobenzylcarbene was achieved by nanosecond laser flash photolysis. Arrhenius activation parameters of Eact = 3.39 ± 0.14 kcal mol-1 and log [A(s-1)] = 10.98 ± 0.14 were obtained for 1,2-chlorine migration in α-methyl-α-chlorobenzyl(ch1oro)carbene. The lifetime of this carbene is considerably longer than previously estimated and the measured Eact, is in excellent agreement with that determined by product analysis.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610050510
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