ISSN:
1434-193X
Keywords:
Fluorine
;
Glycosides
;
Hydrogen bonds
;
Oxidation
;
Peroxides
;
Peroxides
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Aqueous 30% H2O2 in hexafluoro-2-propanol (HFIP) is described as a facile, selective and efficient oxidant for the conversion of sulfides to sulfoxides under neutral conditions. The nitrogen center of the pyridine molecule and the carbon-carbon double bond are shown to not be affected by the reagent system used. The oxidation of glycosyl sulfides to glycosyl sulfoxides was achieved in very high yield at room temperature.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
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