ISSN:
1434-193X
Keywords:
Carbanions
;
Linear Free Energy relationships
;
Marcus theory
;
Solvational imbalances
;
Oximate reactivity
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
We report the first instance of the levelling of oximate reactivity in a deprotonation process, which is shown to have as origin the desolvation of the oximate ion prior to actual proton transfer, in accord with the large predominance of the work term (wr) far exceeding the intrinsic barrier term in the Marcus formulation.Supporting information for this article is available on the WWW under //http://www.wiley-vch.de/contents/jc_2046/1999/99076_s.pdf or from the author.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
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