ISSN:
1432-2234
Keywords:
MNDO
;
Diazirines
;
Methylenediazirine ∼ Reaction of
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The MNDO molecular orbital method gives good agreement between experimental geometries and, when available, heats of formation of diazirines. MNDO and ab initio calculations have been performed on a novel intermediate, methylenediazirine, proposed in a reaction of 3-chloro-3-methyl-diazirine. The relation of this intermediate to its diazo-isomer, its dimer and the products of the reaction are discussed on the basis of MNDO calculations.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00549431
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