ISSN:
1040-0397
Keywords:
γ-CD
;
C60-γ-CD (1:1) inclusion complex
;
Adsorption
;
Cyclic voltammetry
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The electrochemical behavior of the water-soluble C60-γ-CD (1:1) inclusion complex has been studied on the hanging mercury drop electrode. A one-electron reversible adsorptive electroreduction and three irreversible adsorptive electroreductions were detected by cyclic voltammetry. The amount of C60-γ-CD adsorbed at saturation is 1.73 × 10-11 mol/cm2, the diffusion coefficient is 5.81 × 10-6 cm2/s, and the standard rate constant of the surface reaction ks are 0.888 s-1, 0.853 s-1 and 1.032 s-1, respectively.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/elan.1140090611
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