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Ion-solvent interactions: Conductance behavior of NaAlBu4 and Bu4NAlBu4 in benzene and tetrahydrofuran (1974)

Imhof, J. ; Westmoreland, T. D. ; Ray, M. C.

Springer

Journal of solution chemistry 3 (1974), S. 83-89

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ISSN: 1572-8927

Keywords: Conductance ; sodium tetrabutylaluminate ; tetrabutylammonium tetrabutylaluminate ; tetrahydrofuran ; benzene ; ion pairs ; ion aggregates

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Conductance measurements are reported for NaAlBu 4 and Bu 4 NAlBu 4 in benzene and in tetrahydrofuran (THF) from a concentration of approximately 5×10−3 M to the fused state for each salt. This is the first reported study where a comparison of a salt with a small cation is made with one having a large cation in a noncomplexing solvent (benzene) and a complexing solvent (THF). The similarity in conductance behavior in THF and the differences in benzene are considered in terms of ion-ion and ion-solvent interactions.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00646878

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