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Field ionization mass spectrometry of higher n-alkenes (1978)

Rang, S. A. ; Müürisepp, A.-M. A. ; Liitmaa, M. M. ; [et al.]

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 13 (1978), S. 181-183

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: In a strong electric field the molecular ions of n-alkenes ≤C-12 decompose via cleavage of the C—C bond β to the double bond to form the characteristic alkenyl ions that may be used for the identification of positional isomers. For 3-alkenes (〉C-10), 4-, 5- and 6-alkenes the formation of the ions with m/e 54 via double β-cleavage is typical. The field ionization mass spectra of the cis and trans isomers are indistinguishable.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210130402

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