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Digitale Medien

Singlet Oxygen Quenching Abilities of CarotenoidsDedicated to Professor Waldemar Adam on the occasion of his 60th birthday. (1997)

Baltschun, Dietmar ; Beutner, Stefan ; Briviba, Karlis ; [weitere]

Weinheim : Wiley-Blackwell

Liebigs Annalen 1997 (1997), S. 1887-1893

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ISSN: 0947-3440

Schlagwort(e): Carotenoids ; Isonorastacene synthesis ; Singlet oxygen ; Effective chain length ; Second-order quenching rate constants ; Chemistry ; Organic Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The bimolecular rate constants kq for quenching of singlet oxygen (1Δg state) by 26 different natural and novel synthetic carotenoids were determined at 37 °C in a mixture of chloroform and ethanol. The steady-state technique used involves the generation of 1O2 by thermal decomposition of disodium 3,3′-naphtalene-1,4-diyl-dipropionate endoperoxide (NDPO2) and the detection of its luminescence intensity at 1270 nm. Excitation energies (π,π*, 11Ag → 11Bu) and absorption maxima (430-590 nm) vary in the broadest range. Deeply coloured blue carotenoids are also included in the studies for the first time. An empirical correlation between the π,π* (11Ag → 11Bu) excitation energy and carotenoid structure (effective chain length Neff) was found: E(S) = 12642 cm-1 + 92027 cm-1 × 1/Neff. The quenching ability of the investigated carotenoids depends on the excitation energy of their transition at long wavelengths in a characteristic way showing as limiting factors either the thermal Arrhenius activation or the diffusion-controlled rate. This dependence and the suspected relationship between singlet E(S) and triplet E(T) energies, respectively, are discussed.

Zusätzliches Material: 2 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/jlac.199719970913

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Digitale Medien

Biochemistry of Oxidative Stress (1986)

Sies, Helmut

Weinheim : Wiley-Blackwell

Angewandte Chemie International Edition in English 25 (1986), S. 1058-1071

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ISSN: 0570-0833

Schlagwort(e): Oxidative stress ; Stress ; DNA damage ; Antioxidants ; Oxygen ; Inflammation ; Carcinogenesis ; Chemistry ; General Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: As a normal attribute of aerobic life, structural damage to organic compounds of a wide variety (DNA, proteins, carbohydrates and lipids) may occur as a consequence of oxidative reactions. Oxidative damage inflicted by reactive oxygen species has been called “oxidative stress”. Biological systems contain powerful enzymatic and nonenzymatic antioxidant systems, and oxidative stress denotes a shift in the prooxidant/antioxidant balance in favor of the former. Diverse biological processes such as inflammation, carcinogenesis, ageing, radiation damage and photobiological effects appear to involve reactive oxygen species. This field of research provides new perspectives in biochemical pharmacology, toxicology, radiation biochemistry as well as pathophysiology.

Zusätzliches Material: 21 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/anie.198610581

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