Publication Date:
2022-05-25
Description:
Author Posting. © The Authors, 2005. This is the author's version of the work. It is posted here by permission of Springer for personal use, not for redistribution. The definitive version was published in Biogeochemistry 77 (2006): 199-215, doi:10.1007/s10533-005-1036-2.
Description:
Eutrophication is a major agent of change affecting freshwater, estuarine, and marine
systems. It is largely driven by transportation of nitrogen from natural and anthropogenic
sources. Research is needed to quantify this nitrogen delivery and to link the delivery to
specific land-derived sources. In this study we measured nitrogen concentrations and δ15N
values in seepage water entering three freshwater ponds and six estuaries on Cape Cod,
Massachusetts and assessed how they varied with different types of land use. Nitrate
concentrations and δ15N values in groundwater reflected land use in developed and pristine
watersheds. In particular, watersheds with larger populations delivered larger nitrate loads with
higher δ15N values to receiving waters. The enriched δ15N values confirmed nitrogen loading
model results identifying wastewater contributions from septic tanks as the major N source.
Furthermore, it was apparent that N coastal sources had a relatively larger impact on the N
loads and isotopic signatures than did inland N sources further upstream in the watersheds.
This finding suggests that management priorities could focus on coastal sources as a first
course of action. This would require management constraints on a much smaller population.
Description:
This work was supported
by funds from the Woods Hole Oceanographic Institution Sea Grant Program, from the
Cooperative Institute for Coastal and Estuarine Environmental Technology, from
Massachusetts Department of Environmental Protection to Applied Science Associates,
Narragansett, RI, as well as from Palmer/McLeod and NOAA National Estuarine Research
Reserve Fellowships to Kevin Kroeger. This work is the result of research sponsored by NOAA
National Sea Grant College Program Office, Department of Commerce, under Grant No.
NA86RG0075, Woods Hole Oceanographic Institution Sea Grant Project No. R/M-40.
Keywords:
Cape Cod
;
Nitrogen
;
Groundwater
;
Stable isotopes
;
Land use
Repository Name:
Woods Hole Open Access Server
Type:
Preprint
Format:
198655 bytes
Format:
application/pdf
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