ALBERT

Description: The 87Sr/86Sr ratio of sea water has increased gradually over the past 40 Myr, suggesting a concomitant increase in global chemical weathering rates (Raymo et al., 1988, doi:10.1130/0091-7613(1988)016〈0649:IOLCMB〉2.3.CO;2; Capo and DePaolo, 1990, doi:10.1126/science.249.4964.51; Hodell et al., 1990, doi:10.1016/0168-9622(90)90011-Z; Raymo and Ruddiman, 1992, doi:10.1038/359117a0; Caldeira, 1992, doi:10.1038/357578a0; Palmer and Edmons, 1992, doi:10.1016/0016-7037(92)90332-D). Recently, Dia et al. (1992, doi:10.1038/356786a0) analysed a 250-kyr 87Sr/86Sr record, and found superimposed on this gradual increase higher-frequency 87Sr/86Sr variations which appeared to follow a 100-kyr cycle; this periodicity corresponds to one of the prominent cycles in the Earth's orbital parameters, which are known to modulate the patterns of solar insolation and hence climate (Berger, 1978, doi:10.1016/0033-5894(78)90064-9; 1989, doi:10.1016/1040-6182(89)90016-5; Imbrie et al., 1992, doi:10.1029/92PA02253). The resolution of this record was, however, insufficient to establish the phase relationship between the 87Sr/86Sr variations and global climate cycles. Here we present a high-resolution seawater 87Sr/86Sr record spanning the past 450 kyr. We find that maxima and minima in 87Sr/86Sr coincide with minima and maxima, respectively, in continental ice volume (from the SPECMAP oxygen isotope record (Imbrie et al., 1984)), apparently suggesting that there was less chemical weathering in arid glacial periods than in the more humid interglacials. During glacial-interglacial transitions, however, seawater 87Sr/86Sr changes at a rate of ~1 p.p.m./kyr, approximately three times that evaluated by Dia et al. (1992, doi:10.1038/356786a0). Mass-balance calculations illustrate that simple changes in modern chemical weathering regimes cannot fully account for such rapid changes, suggesting that we need to revise current ideas about strontium reservoirs and the mechanisms for exchange between them.