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  • Wiley-Blackwell  (2)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 49 (1993), S. 657-671 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A phase-separated epoxy blend containing a sulfonium salt cationic photoinitiator was studied. The onium salt was found to be preferentially soluble in one of the resins of the system. Scanning electron microscopy and microprobe analyses were done to determine the concentration distribution in the phases and the results compared to a model based on liquid extraction distribution coefficient behavior. Finally, the photolithographic behavior of various blends of the epoxy resins is discussed and the results compared to the behavior predicted by the photoinitiator distribution. © 1993 John Wiley & Sons, Inc.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 41 (1990), S. 1753-1764 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An epoxy formulation developed for a photoimaging application was found to exhibit poor clean-out in the developing solvent depending on the lot of one of the base resins. Size exclusion chromatographic (SEC) analysis of the residual material showed it to be a high molecular weight (Mw) fraction of the base resin EpiRez SU-8. The resin was fractionated, and it was demonstrated that removing the high Mw fraction from the formulation enhanced its developability. Lower Mw versions of this resin were evaluated and found to be unsuitable. However, blending one of these resins (EpiRez SU-6) with the SU-8 resulted in a formulation that exhibited excellent developability. Mathematical relationships were calculated that enabled blends to be made, resulting in a defined molecular weight regardless of the lots of resins used.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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