Publication Date:
2013-12-12
Description:
[1] Simultaneous in-situ measurements of ozone, CO, and NO y have been made for the first time at an high altitude site Nainital (29.37 o N, 79.45 o E, 1958 m amsl) in the central Himalayas during 2009-2011. CO and NO y levels discern slight enhancements during the daytime, unlike in ozone. The diurnal patterns are attributed mainly to the dynamical processes including vertical winds and the boundary layer evolution. Springtime higher levels of ozone (57.5 ± 12.6 ppbv), CO (215.2 ± 147 ppbv), and NO y (1918 ± 1769.3 pptv) have been attributed mainly to the regional pollution supplemented with northern Indian biomass burning. However, lower levels of ozone (34.4 ± 18.9 ppbv), CO (146.6 ± 71 ppbv), and NO y (1128.6 ± 1035 pptv) during summer-monsoon are shown to be associated with the arrival of air-mass originated from marine regions. Downward transport from higher altitudes is estimated to enhance surface ozone levels over Nainital by 6.1 - 18.8 ppbv. The classification based on air-mass residence time, the altitude variations along trajectory and the boundary layer shows higher levels of ozone (57 ± 14 ppbv), CO (206 ± 125 ppbv), and NO y (1856 ± 1596 pptv), in the continental air-masses when compared with their respective values (28 ± 13 ppbv, 142 ± 47 ppbv, and 226 ± 165 pptv) in the regional background air-masses. In general, positive inter-species correlations are observed which suggest the transport of air-mass from common source regions (except during winter). Ozone–CO and ozone-NO y slope values are found to be lower in comparison to those at other global sites, which clearly indicates the incomplete in-situ photochemistry and greater role of transport processes in this region. The higher CO/NO y value also confirms minimal influence of the fresh emissions at the site. Enhancements in ozone, CO, and NO y during high fire activity period are estimated to be 4-18%, 15-76%, and 35-51% respectively. Despite higher CO and NO y concentrations at Nainital, ozone levels are nearly similar to those at other global high altitude sites.
Print ISSN:
0148-0227
Topics:
Geosciences
,
Physics
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