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  • 1
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    Lithium in the aragonite skeletons of massive Porites corals: A new tool to reconstruct tropical sea surface temperatures (2013)
    AGU (American Geophysical Union) | Wiley
    In:  Paleoceanography, 28 (1). pp. 143-152.
    Details
    Publication Date: 2017-05-10
    Description: Previous studies have demonstrated the potential for the Li content of coral aragonite to record information about environmental conditions, but no detailed study of tropical corals exists. Here we present the Li and Mg to Ca ratios at a bimonthly to monthly resolution over 25 years in two modern Porites corals, the genus most often used for paleoclimate reconstructions in the tropical Indo-Pacific. A strong relationship exists between coral Li/Ca and locally measured SST, indicating that coral Li/Ca can be used to reconstruct tropical SST variations. However, Li/Ca ratios of the skeleton deposited during 1979-1980 do not track local SST well and are anomalously high in places. The Mg/Ca ratios of this interval are also anomalously high, and we suggest Li/Ca can be used to reconstruct tropical SST only when Mg/Ca data are used to carefully screen for relatively rare biological effects. Mg/Li or Li/Mg ratios provide little advantage over Li/Ca ratios, except that the slope of the Li/Mg temperature relationship is more similar between the two corals. The Mg/Li temperature relationship for the coral that experienced a large temperature range is similar to that found for cold water corals and aragonitic benthic foraminifera in previous studies. The comparison with data from other biogenic aragonites suggests the relationship between Li/Mg and water temperature can be described by a single exponential relationship. Despite this hint at an overarching control, it is clear that biological processes strongly influence coral Li/Ca, and more calibration work is required before widely applying the proxy
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  • 2
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    Role of the Deglacial Buildup of the Great Barrier Reef for the Global Carbon Cycle (2022)
    AGU (American Geophysical Union) | Wiley
    Details
    Publication Date: 2024-02-07
    Description: The carbon isotope 13C is commonly used to attribute the last deglacial atmospheric CO2 rise to various processes. Here we show that the growth of the world's largest reef system, the Great Barrier Reef (GBR), is marked by a pronounced decrease in δ13C in absolutely dated fossil coral skeletons between 12.8 and 11.7 ka, which coincides with a prominent minimum in atmospheric δ13CO2 and the Younger Dryas. The event follows the flooding of a large shelf platform and initiation of an extensive barrier reef system at 13 ka. Carbon cycle simulations show the coral δ13C decrease was mainly caused by the combination of isotopic fractionation during reef carbonate production and the decomposition of organic land carbon on the newly flooded shallow-water platform. The impacts of these processes on atmospheric CO2 and δ13CO2, however, are marginal. Thus, the GBR was not contributing to the last deglacial δ13CO2 minimum at ∼12.4 ka.
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  • 3
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    Interlaboratory study for coral Sr/Ca and other element/Ca ratio measurements (2013)
    AGU (American Geophysical Union) | Wiley
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    Publication Date: 2024-03-22
    Description: The Sr/Ca ratio of coral aragonite is used to reconstruct past sea surface temperature (SST). Twentyone laboratories took part in an interlaboratory study of coral Sr/Ca measurements. Results show interlaboratory bias can be significant, and in the extreme case could result in a range in SST estimates of 7°C. However, most of the data fall within a narrower range and the Porites coral reference material JCp- 1 is now characterized well enough to have a certified Sr/Ca value of 8.838 mmol/mol with an expanded uncertainty of 0.089 mmol/mol following International Association of Geoanalysts (IAG) guidelines. This uncertainty, at the 95% confidence level, equates to 1.5°C for SST estimates using Porites, so is approaching fitness for purpose. The comparable median within laboratory error is 〈0.5°C. This difference in uncertainties illustrates the interlaboratory bias component that should be reduced through the use of reference materials like the JCp-1. There are many potential sources contributing to biases in comparative methods but traces of Sr in Ca standards and uncertainties in reference solution composition can account for half of the combined uncertainty. Consensus values that fulfil the requirements to be certified values were also obtained for Mg/Ca in JCp-1 and for Sr/Ca and Mg/Ca ratios in the JCt-1 giant clam reference material. Reference values with variable fitness for purpose have also been obtained for Li/Ca, B/Ca, Ba/Ca, and U/Ca in both reference materials. In future, studies reporting coral element/Ca data should also report the average value obtained for a reference material such as the JCp-1.
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  • 4
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    Pacing of Red Sea Deep Water Renewal During the Last Centuries (2019)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 46(8), pp. 4413-4420, ISSN: 0094-8276
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    Publication Date: 2019-10-07
    Description: The Red Sea is a deep marine basin often considered as small‐scale version of the global ocean. Hydrographic observations and ocean‐atmosphere modeling indicate Red Sea deep water was episodically renewed by wintertime open‐ocean deep convections during 1982–2001, suggesting a renewal time on the order of a decade. However, the long‐term pacing of Red Sea deep water renewals is largely uncertain. We use an annually resolved coral oxygen isotope record of winter surface water conditions to show that the late twentieth century deep water renewals were probably unusual in the context of the preceding ~100 years. More frequent major events are detected during the late Little Ice Age, particularly during the early nineteenth century characterized by large tropical volcanic eruptions. We conclude that Red Sea deep water renewal time is on the order of a decade up to a century, depending on the mean climatic conditions and large‐scale interannual climate forcing.
    Repository Name: EPIC Alfred Wegener Institut
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  • 5
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    Interlaboratory study for coral Sr/Ca and other element/Ca ratio measurements (2013)
    Wiley
    In:  EPIC3Geochemistry Geophysics Geosystems, Wiley, 14(9), pp. 3730-3750, ISSN: 1525-2027
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    Publication Date: 2015-10-21
    Repository Name: EPIC Alfred Wegener Institut
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  • 6
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    Mild and arid climate in the eastern Sahara‐Arabian Desert during the late Little Ice Age (2018)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 45, ISSN: 0094-8276
    Details
    Publication Date: 2018-07-30
    Description: The climate of the Sahara and Arabian Deserts during the Little Ice Age is not well known, due to a lack of annually resolved natural and documentary archives. We present an annual reconstruction of temperature and aridity derived from Sr/Ca and oxygen isotopes in a coral of the desert‐surrounded northern Red Sea. Our data indicate that the eastern Sahara and Arabian Deserts did not experience pronounced cooling during the late Little Ice Age (~1750–1850) but suggest an even more arid mean climate than in the following ~150 years. The mild temperatures are broadly in line with predominantly negative phases of the North Atlantic Oscillation during the Little Ice Age. The more arid climate is best explained by meridional advection of dry continental air from Eurasia. We find evidence for an abrupt termination of the more arid climate after 1850, coincident with a reorganization of the atmospheric circulation over Europe.
    Repository Name: EPIC Alfred Wegener Institut
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  • 7
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    Distinct modes of East Asian Winter Monsoon documented by a southern Red Sea coral record (2014)
    Wiley
    In:  EPIC3Journal of Geophysical Research-Oceans, Wiley, ISSN: 2169-9291
    Details
    Publication Date: 2016-12-09
    Description: The large-scale boreal winter climatic patterns associated with interannual variability in a coral oxygen isotope (δ18O) record from the southern Red Sea (Klein et al. [1997]) covering most of the last century are investigated. From the early 1930’s to the early 1960’s, the winter coral δ18O record, reflecting temperature and salinity variations in southern Red Sea surface waters, is associated with global (or large scale) sea surface temperature (SST) and 850mb geopotential height (Z850) anomalies which project on the corresponding patterns associated with the El Niño-Southern Oscillation (ENSO). In contrast, since the early 1960’s the winter coral δ18O record is related to a Z850 pattern that reflects the ENSO-independent part of the East Asian Winter Monsoon (EAWM), which includes the Siberian High, the East Asian through and the East Asian upper-tropospheric Jet. Our results indicate a weakening of the ENSO control on interannual temperature/salinity variations in southern Red Sea surface waters in the early 1960’s, due to the warming of the Indian Ocean, and suggest that information about the non-stationarity in the relationship between ENSO and two distinct modes of EAWM can be documented in southern Red Sea coral δ18O records.
    Repository Name: EPIC Alfred Wegener Institut
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  • 8
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    Tropical Atlantic Cooling and Freshening in the Middle of the Last Interglacial From Coral Proxy Records (2019)
    Wiley
    In:  EPIC3Geophysical Research Letters, Wiley, 46(14), pp. 8289-8299, ISSN: 0094-8276
    Details
    Publication Date: 2019-10-07
    Description: The last interglacial (LIG; Marine Isotope Substage 5e, ~127–117 ka) experienced globally warmer than modern temperatures; however, profound differences in regional climate occurred that are relevant to the assessment of future climate change scenarios. Tropical Atlantic sea surface temperature (SST) and hydrology are intrinsic to the spatiotemporal evolution of past and future climate. We present eight monthly resolved coral Sr/Ca and δ18O records (130–118 ka) to reconstruct mean western tropical Atlantic SST and seawater δ18O changes during the LIG. Cooler and fresher than modern surface waters are indicated for the middle of the LIG at ~126 ka. This was followed by a rapid transition to modern‐like SSTs and salinities that characterized the remaining part of the LIG. Our results, which account for differences found among corals, proxies, and SST calibration uncertainties, agree with western tropical Atlantic sediment records. Together, they suggest that an oceanic regime existed that differed from today.
    Repository Name: EPIC Alfred Wegener Institut
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