ALBERT

Description: Geochemical variations in shallow water corals provide a valuable archive of paleoclimatic information. However, biological effects can complicate the interpretation of these proxies, forcing their application to rely on empirical calibrations. Carbonate clumped isotope thermometry (Delta47) is a novel paleotemperature proxy based on the temperature dependent "clumping" of 13C-18O bonds. Similar ?47-temperature relationships in inorganically precipitated calcite and a suite of biogenic carbonates provide evidence that carbonate clumped isotope variability may record absolute temperature without a biological influence. However, large departures from expected values in the winter growth of a hermatypic coral provided early evidence for possible Delta47 vital effects. Here, we present the first systematic survey of Delta47 in shallow water corals. Sub-annual Red Sea Delta47 in two Porites corals shows a temperature dependence similar to inorganic precipitation experiments, but with a systematic offset toward higher Delta47 values that consistently underestimate temperature by ~8 °C. Additional analyses of Porites, Siderastrea, Astrangia and Caryophyllia corals argue against a number of potential mechanisms as the leading cause for this apparent Delta47 vital effect including: salinity, organic matter contamination, alteration during sampling, the presence or absence of symbionts, and interlaboratory differences in analytical protocols. However, intra- and inter-coral comparisons suggest that the deviation from expected Delta47 increases with calcification rate. Theoretical calculations suggest this apparent link with calcification rate is inconsistent with pH-dependent changes in dissolved inorganic carbon speciation and with kinetic effects associated with CO2 diffusion into the calcifying space. However, the link with calcification rate may be related to fractionation during the hydration/hydroxylation of CO2 within the calcifying space. Although the vital effects we describe will complicate the interpretation of Delta47 as a paleothermometer in shallow water corals, it may still be a valuable paleoclimate proxy, particularly when applied as part of a multi-proxy approach.

Description: The climate of the Sahara and Arabian deserts during the Little Ice Age is not well known, due to a lack of annually resolved natural and documentary archives. We present an annual reconstruction of temperature and aridity derived from Sr/Ca and oxygen isotopes in a coral of the desert-surrounded northern Red Sea. Our data indicate that the eastern Sahara and Arabian Desert did not experience pronounced cooling during the late Little Ice Age (~1750-1850), but suggest an even more arid mean climate than in the following ~150 years. The mild temperatures are broadly in line with predominantly negative phases of the North Atlantic Oscillation during the Little Ice Age. The more arid climate is best explained by meridional advection of dry continental air from Eurasia. We find evidence for an abrupt termination of the more arid climate after 1850, coincident with a reorganization of the atmospheric circulation over Europe.

Description: Here we present 230Th/U, 231Pa/U as well as 226Ra/230Th isotope ratios from five fossil reef corals of Last Interglacial origin from the Gulf of Aqaba, Northern Red Sea. The results show clear evidence for open-system behaviour with strongly elevated δ234U values and U concentrations indicating post-depositional U addition. The combined application of all isotope systems enables us to better constrain the nature and timing of the open-system processes than only based on the 230Th/U data. Quantitative modelling of the diagenetic processes allowed us to reproduce the trends in the isotope ratios. Two of the five corals were probably affected by two separate phases of U addition with different δ234U values. The trends observed for two other corals can be explained by U addition followed by U loss. The fifth coral shows signs of both U gain and loss at the same time in the more recent past. The timing of the diagenetic processes is remarkably similar for the five corals and can be constrained to approx. 1 and 6 thousand years (ka) and 100 and 102 ka after coral growth, respectively. Based on the modelling results, we suggest that conventional 231Pa/230Th ages provide the best estimate for the true age of four of the five corals, which range from 109.1 to 114.1 ka. This implies a late Last Interglacial time of deposition. For the fifth coral, the most reliable age estimate is the conventional 230Th/U age of one of the subsamples (117.3 ka), based on a concordia diagram for all subsamples. The timing of the modelled open-system processes suggests that the early event of U addition was associated with interaction of the corals with 234U-enriched seawater or saline groundwater. The later open-system event can be described as U redistribution within the coral reef, since some corals apparently lost U while others gained U. The timing of the second event is broadly consistent with the Bølling-Allerød interstadial, which was probably characterised by enhanced wetness in this typically hyper-arid region.

Description: Instrumental climate observations provide robust records of global land and ocean temperatures during the twentieth century. Unlike for temperature, continuous salinity observations in the surface ocean are scarce prior to 1970, and the magnitude of salinity changes during the twentieth century is largely unknown. Surface ocean salinity is a major component in climate dynamics, as it influences ocean circulation and water mass formation. Here we present an annually resolved reconstruction of salinity variations in the surface waters of the western subtropical North Pacific Ocean since 1873, based on bimonthly records of d18O, Sr/Ca, and U/Ca in a coral from the Ogasawara Islands. The reconstruction indicates that an abrupt regime shift toward fresher surface ocean conditions occurred between 1905 and 1910. Observational atmospheric data suggest that the abrupt freshening was associated with a weakening of the winds that drive the Kuroshio Current system and the associated subtropical gyre circulation. We note that the abrupt early-twentieth-century freshening in the western subtropical North Pacific precedes abrupt climate change in the northern North Atlantic by a few years. The potential for abrupt regime shifts in surface ocean salinity should be considered in climate predictions for the coming decades.