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  • Mineralogical Society of America  (4)
  • Oxford, London, Edinburgh, Boston, Melbourne : Blackwell Scientific Publications  (1)
  • 1
    Unknown
    Oxford, London, Edinburgh, Boston, Melbourne : Blackwell Scientific Publications
    Keywords: Aufschiebung ; Überschiebung ; Tektonik ; Erdkruste ; Inversions (Geology)
    Description / Table of Contents: M. A. Cooper and G. D. Williams: Introduction / Geological Society, London, Special Publications, 44:vii, doi:10.1144/GSL.SP.1989.044.01.01 --- Modelling and Theoretical Concepts --- G. D. Williams, C. M. Powell, and M. A. Cooper: Geometry and kinematics of inversion tectonics / Geological Society, London, Special Publications, 44:3-15, doi:10.1144/GSL.SP.1989.044.01.02 --- A. B. Hayward and R. H. Graham: Some geometrical characteristics of inversion / Geological Society, London, Special Publications, 44:17-39, doi:10.1144/GSL.SP.1989.044.01.03 --- K. R. McClay: Analogue models of inversion tectonics / Geological Society, London, Special Publications, 44:41-59, doi:10.1144/GSL.SP.1989.044.01.04 --- Inversion in the Alps and Alpine Foreland --- P. A. Ziegler: Geodynamic model for Alpine intra-plate compressional deformation in Western and Central Europe / Geological Society, London, Special Publications, 44:63-85, doi:10.1144/GSL.SP.1989.044.01.05 --- P. C. de Graciansky, G. Dardeau, M. Lemoine, and P. Tricart: The inverted margin of the French Alps and foreland basin inversion / Geological Society, London, Special Publications, 44:87-104, doi:10.1144/GSL.SP.1989.044.01.06 --- R. W. H. Butler: The influence of pre-existing basin structure on thrust system evolution in the Western Alps / Geological Society, London, Special Publications, 44:105-122, doi:10.1144/GSL.SP.1989.044.01.07 --- I. R. Simpson, M. Gravestock, D. Ham, H. Leach, and S. D. Thompson: Notes and cross-sections illustrating inversion tectonics in the Wessex Basin / Geological Society, London, Special Publications, 44:123-129, doi:10.1144/GSL.SP.1989.044.01.08 --- D. G. Roberts: Basin inversion in and around the British Isles / Geological Society, London, Special Publications, 44:131-150, doi:10.1144/GSL.SP.1989.044.01.09 --- Inversion on the European Continental Shelf --- J. A. Cartwright: The kinematics of inversion in the Danish Central Graben / Geological Society, London, Special Publications, 44:153-175, doi:10.1144/GSL.SP.1989.044.01.10 --- T. J. Chapman: The Permian to Cretaceous structural evolution of the Western Approaches Basin (Melville sub-basin), UK / Geological Society, London, Special Publications, 44:177-200, doi:10.1144/GSL.SP.1989.044.01.11 --- M. E. Badley, J. D. Price, and L. C. Backshall: Inversion, reactivated faults and related structures: seismic examples from the southern North Sea / Geological Society, London, Special Publications, 44:201-219, doi:10.1144/GSL.SP.1989.044.01.12 --- Inversion in Other Geological Environments --- C. M. Powell and G. D. Williams: The Lewis Thrust/Rocky Mountain trench fault system in Northwest Montana, USA: an example of negative inversion tectonics? / Geological Society, London, Special Publications, 44:223-234, doi:10.1144/GSL.SP.1989.044.01.13 --- K. R. McClay, M. W. Insley, and R. Anderton: Inversion of the Kechika Trough, Northeastern British Columbia, Canada / Geological Society, London, Special Publications, 44:235-257, doi:10.1144/GSL.SP.1989.044.01.14 --- C. K. Morley: Basin inversion in the Osen-Røa thrust sheet, Southern Norway / Geological Society, London, Special Publications, 44:259-273, doi:10.1144/GSL.SP.1989.044.01.15 --- M. P. Coward, M. A. Enfield, and M. W. Fischer: Devonian basins of Northern Scotland: extension and inversion related to Late Caledonian — Variscan tectonics / Geological Society, London, Special Publications, 44:275-308, doi:10.1144/GSL.SP.1989.044.01.16 --- M. C. Daly, J. Chorowicz, and J. D. Fairhead: Rift basin evolution in Africa: the influence of reactivated steep basement shear zones / Geological Society, London, Special Publications, 44:309-334, doi:10.1144/GSL.SP.1989.044.01.17 --- M. A. Cooper, G. D. Williams, P. C. de Graciansky, R. W. Murphy, T. Needham, D. de Paor, R. Stoneley, S. P. Todd, J. P. Turner, and P. A. Ziegler: Inversion tectonics — a discussion / Geological Society, London, Special Publications, 44:335-347, doi:10.1144/GSL.SP.1989.044.01.18 --- Abstracts --- I. W. D. Dalziel: Inversion of circum-Pacific marginal basins / Geological Society, London, Special Publications, 44:351, doi:10.1144/GSL.SP.1989.044.01.19 --- J. F. Dewey: Kinematics and dynamics of basin inversion / Geological Society, London, Special Publications, 44:352, doi:10.1144/GSL.SP.1989.044.01.20 --- A. Gibbs and A. Beach: Extensional tectonics in a convergent intra-plate setting: linked inversions on oblique and frontal ramps / Geological Society, London, Special Publications, 44:353, doi:10.1144/GSL.SP.1989.044.01.21 --- R. Gillcrist, M. P. Coward, B. Trudgill, A. Pecher, and J. L. Mugnier: Structural inversion in the external French Alps / Geological Society, London, Special Publications, 44:354, doi:10.1144/GSL.SP.1989.044.01.22 --- N. J. Kusznir and G. D. Williams: Geometric, thermal and isostatic constraints on basin inversion / Geological Society, London, Special Publications, 44:355, doi:10.1144/GSL.SP.1989.044.01.23 --- B. van Hoorn: Structural evolution, timing and tectonic style of the Sole Pit inversion / Geological Society, London, Special Publications, 44:356, doi:10.1144/GSL.SP.1989.044.01.24
    Pages: Online-Ressource (VII, 375 Seiten) , Illustrationen, Diagramme, Karten
    ISBN: 0632025026
    Language: English
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  • 2
    Publication Date: 2017-06-02
    Description: Zoned crystals of carbocernaite occur in hydrothermally reworked burbankite-fluorapatite-bearing calcite carbonatite at Bear Lodge, Wyoming. The mineral is paragenetically associated with pyrite, strontianite, barite, ancylite-(Ce), and late-stage calcite, and is interpreted to have precipitated from sulfate-bearing fluids derived from an external source and enriched in Na, Ca, Sr, Ba, and rare-earth elements (REE) through dissolution of the primary calcite and burbankite. The crystals of carbocernaite show a complex juxtaposition of core-rim, sectoral, and oscillatory zoning patterns arising from significant variations in the content of all major cations, which can be expressed by the empirical formula (Ca 0.43–0.91 Sr 0.40–0.69 REE 0.18–0.59 Na 0.18–0.53 Ba 0–0.08 ) 1.96–2.00 (CO 3 ) 2 . Interelement correlations indicate that the examined crystals can be viewed as a solid solution between two hypothetical end-members, CaSr(CO 3 ) 2 and NaREE(CO 3 ) 2 , with the most Na-REE-rich areas in pyramidal (morphologically speaking) growth sectors representing a probable new mineral species. Although the Bear Lodge carbocernaite is consistently enriched in light REE relative to heavy REE and Y (chondrite-normalized La/Er = 500–4200), the pyramidal sectors exhibit a greater degree of fractionation between these two groups of elements relative to their associated prismatic sectors. A sample approaching the solid-solution midline [(Ca 0.57 Na 0.42 ) 0.99 (Sr 0.50 REE 0.47 Ba 0.01 ) 0.98 (CO 3 ) 2 ] was studied by single-crystal X-ray diffraction and shown to have a monoclinic symmetry [space group P 11 m , a = 6.434(4), b = 7.266(5), c = 5.220(3) Å, = 89.979(17)°, Z = 2] as opposed to the orthorhombic symmetry (space group Pb 2 1 m ) proposed in earlier studies. The symmetry reduction is due to partial cation order in sevenfold-coordinated sites occupied predominantly by Ca and Na, and in tenfold-coordinated sites hosting Sr, REE, and Ba. The ordering also causes splitting of carbonate vibrational modes at 690–740 and 1080–1100 cm –1 in Raman spectra. Using Raman micro-spectroscopy, carbocernaite can be readily distinguished from burbankite- and ancylite-group carbonates characterized by similar energy-dispersive spectra.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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  • 3
    Publication Date: 2017-05-02
    Description: Rowleyite, $$[\mathrm{Na}{({\mathrm{NH}}_{4},\mathrm{K})}_{9}{\mathrm{Cl}}_{4}]{[{\mathrm{V}}_{2}^{5+,4+}(\mathrm{P},\mathrm{As}){\mathrm{O}}_{8}]}_{6}\cdot n[{\mathrm{H}}_{2}\mathrm{O},\mathrm{Na},{\mathrm{NH}}_{4},\mathrm{K},\mathrm{Cl}]$$ , is a new mineral species from the Rowley mine, Maricopa County, Arizona, U.S.A. It was found in an unusual low-temperature, apparently post-mining suite of phases that include various vanadates, phosphates, oxalates, and chlorides, some containing $${\mathrm{NH}}_{4}^{+}$$ . Other secondary minerals found in association with rowleyite are antipinite, fluorite, mimetite, mottramite, quartz, salammoniac, struvite, vanadinite, willemite, wulfenite, and several other potentially new minerals. Analyzed 13 C values for the antipinite in association with rowleyite are consistent with a bat guano source. Crystals of rowleyite are very dark brownish green (appearing black) truncated octahedra up to about 50 μm in diameter. The streak is brownish green, the luster is vitreous, very thin fragments are transparent. The Mohs hardness is about 2, the tenacity is brittle, fracture is irregular, there is no cleavage, and the measured density is 2.23(2) g/cm 3 . Rowleyite is optically isotropic with n = 1.715(5). Electron microprobe analyses yielded the empirical formula $${[{({\mathrm{NH}}_{4})}_{8.81}{\mathrm{Na}}_{3.54}{\mathrm{K}}_{2.58})}_{\Sigma 14.93}{\mathrm{Cl}}_{6.29}{({\mathrm{H}}_{2}\mathrm{O})}_{16}][{({\mathrm{V}}_{9.36}^{5+}{\mathrm{V}}_{2.64}^{4+})}_{\Sigma 12}{({\mathrm{P}}_{5.28}{\mathrm{As}}_{0.72}^{5+})}_{\Sigma 6}{\mathrm{O}}_{48}]$$ . Raman and infrared spectroscopy confirmed the presence of NH 4 and H 2 O. Rowleyite is cubic, $$Fd\overline{3}m$$ , with a = 31.704(14) Å, V = 31867(42) Å 3 , and Z = 16. The crystal structure of rowleyite ( R 1 = 0.040 for 1218 F o 〉 4 F reflections) contains [V 4 O 16 ] 12+ polyoxovanadate units that link to one another via shared vertices with [(P,As)O 4 ] 3– tetrahedra to form a 3D framework possessing large interconnected channels. The channels contain a 3D ordered [Na(NH 4 ,K) 9 Cl 4 ] 6+ salt net, which apparently served as a template for the formation of the framework. In that respect, rowleyite can be considered a salt-inclusion solid (SIS). The rowleyite framework is among the most porous known.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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  • 4
    Publication Date: 2014-01-03
    Description: Vladykinite, ideally Na 3 Sr 4 (Fe 2+ Fe 3+ )Si 8 O 24 , is a new complex sheet silicate occurring as abundant prismatic crystals in a dike of coarse-grained peralkaline feldspathoid syenite in the north-central part of the Murun complex in eastern Siberia, Russia (Lat. 58° 22' 48'' N; Long. 119° 03' 44'' E). The new mineral is an early magmatic phase associated with aegirine, potassium feldspar, eudialyte, lamprophyllite, and nepheline; strontianite (as pseudomorphs after vladykinite) and K-rich vishnevite are found in the same assemblage, but represent products of late hydrothermal reworking. Vladykinite is brittle, has a Mohs hardness of 5, and distinct cleavage on {100}. In thin section, it is colorless, biaxial negative [α = 1.624(2), β = 1.652(2), = 1.657(2), 2 V meas = 44(1)°, 2 V calc = 45(1)°] and shows an optic orientation consistent with its structural characteristics ( X^a = 5.1° in β obtuse, Z^c = 4.7° in β acute, Y = b ). The Raman spectrum of vladykinite consists of the following vibration modes (listed in order of decreasing intensity): 401, 203, 465, 991, 968, 915, 348, 167, 129, 264, 1039, and 681 cm –1 ; O-H signals were not detected. The Mössbauer spectrum indicates that both Fe 2+ and Fe 3+ are present in the mineral (Fe 3+ /Fe = 0.47), and that both cations occur in a tetrahedral coordination. The mean chemical composition of vladykinite (acquired by wavelength-dispersive X-ray spectrometry and laser-ablation inductively-coupled-plasma mass-spectrometry), with Fe recast into Fe 2+ and Fe 3+ in accord with the Mössbauer data, gives the following empirical formula calculated to 24 O atoms: (Na 2.45 Ca 0.56 ) 3.01 (Sr 3.81 K 0.04 Ba 0.02 La 0.02 Ce 0.01 ) 3.90 (Fe 2+ 0.75 Fe 3+ 0.66 Mn 0.26 Zn 0.16 Al 0.12 Mg 0.05 Ti 0.01 ) 2.01 (Si 7.81 Al 0.19 ) 8.00 O 24 . The mineral is monoclinic, space group P 2 1 / c , a = 5.21381(13), b = 7.9143(2), c = 26.0888(7) Å, β = 90.3556(7)°, V = 1076.50(5) Å 3 , Z = 2. The ten strongest lines in the powder X-ray diffraction pattern are [ d obs in Å ( I ) ( hkl )]: 2.957 (100) (23, 123); 2.826 (100) (17, 117); 3.612 (58) (14, 114); 3.146 (37) (120); 2.470 (32) (210, 01.10); 4.290 (30) (11, 111); 3.339 (30) (06, 115, 106); 2.604 (28) (200); 2.437 (25) (034); 1.785 (25) (21.10, 34). The structure of vladykinite, refined by single-crystal techniques on the basis of 3032 reflections with F o 〉 4 F o to R 1 = 1.6%, consists of tetrahedral sheets parallel to (100) and consisting of (Si 8 O 24 ) 16– units incorporating four-membered silicate rings and joined into five- and eight-membered rings by sharing vertices with larger tetrahedra hosting Fe 2+ , Fe 3+ , Mn, Zn, Al, Mg, and Ti. Larger cations (predominantly Na, Sr, and Ca) are accommodated in octahedral and square-antiprismatic interlayer sites sandwiched between the tetrahedral sheets. Structural relations between vladykinite and other sheet silicates incorporating four-, five-, and eight-membered rings are discussed. The name vladykinite is in honor of Nikolay V. Vladykin (Vinogradov Institute of Geochemistry, Russia), in recognition of his contribution to the study of alkaline rocks. Holotype and co-type specimens of the mineral were deposited in the Robert B. Ferguson Museum of Mineralogy in Winnipeg, Canada.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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  • 5
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