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  • Wiley-Blackwell  (2)
  • 1975-1979  (2)
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  • Wiley-Blackwell  (2)
  • Wiley  (4)
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  • 1
    Electronic Resource
    Electronic Resource
    Einschiebungsreaktionen in die Organothallium(III)-Element-Bindung (1976)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 423 (1976), S. 144-154 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Insertion Reactions to the Organothallium (III)-Element BondInsertion reactions to the thallium-element bonds of Me2Tl-NMe2 and Me2TI-OEt with RNCS, PhNCO, CS2. COS, CO2, SO2 and SO3 and the characterization of the reaction products with the chemical and spectroscopic methods are reported.
    Notes: Es wird über Einschiebungsreaktionen in die Thallium-Element-Bindungen von Me2TI-NMe2 bzw. Me2TI-OEt mit RNCS, PhNCO, CS2, COS, CO2, SO2 und SO3 sowie die Charakterisierung der Reaktionsprodukte mit chemischen und spektroskopischen Methoden berichtet.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19764230208
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  • 2
    Electronic Resource
    Electronic Resource
    NMR-Untersuchungen an dimeren Dialkylthallium-Verbindungen mit (TIX)2-Vierringstruktur (1979)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 450 (1979), S. 70-78 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: NMR Investigations on Dimeric Dialkylthallium Compoounds with (TIX)2 Four-membered Ring StructureNMR investigations on dimeric dialkylthallium amides and on dimethylthallium diphenylphosphide indicate a significant influence of the largeness of the bridging groups on the binding strength in the (TIX)2-four-membered ring structure. Exchange reactions among different dimeric dialkylthallium compounds give evidence of a dimer-monomer equilibrium, which is of fundamental importance for the reactivity and the reaction mechanisms of these compounds.
    Notes: NMR-Untersuchungen an dimeren Dialkylthalliumamiden und am Dimethylthalliumdiphenylphosphid indizieren einen signifikanten Einfluß der Größe der Brückengruppen auf die Bindungsstärke in den (TIX)2-Vierringen. Austauschreaktionen zwischen unterschiedlichen dimeren Dialkylthalliumverbindungen beweisen ein Dimer-Monomer-Gleichgewicht, das von grundsätzlicher Bedeutung für die Reaktivität und die Reaktionsmechanismen dieser Verbindungen ist.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19794500110
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    Paper (German National Licenses)
    Fulltext
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