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  • 1
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Regrown/processed AlGaAs interfaces using secondary ion mass spectrometry, cross section transmission electron microscopy (TEM), and reflection high energy electron diffraction have been characterized. Two sets of samples, GaAs/Al0.4Ga0.6As (with GaAs on top) and Al0.4Ga0.6As/GaAs (with Al0.4Ga0.6As on top), are used as starting materials. For the GaAs/Al0.4Ga0.6As samples that are first exposed to atmosphere, the experiment is performed in an integrated processing system where etching and regrowth chambers are linked together by ultrahigh vacuum transfer modules. The etching process includes electron cyclotron resonance (ECR) hydrogen plasma cleaning of GaAs native oxides, ECR SiCl4 plasma anisotropic deep etching into Al0.4Ga0.6As, and an optional, brief Cl2 chemical etching. Regrowth is carried out using solid-source molecular beam epitaxy (MBE). Despite the in situ processing, significant amounts of C, Si, and O impurities at the 10, 5, and 50×1012 cm−2 levels exist at the interfaces. However, the impurity level is one order of magnitude smaller than that in air-exposed, ECR plasma etched and MBE regrown Al0.4Ga0.6As/GaAs of the set 2 samples. As revealed using TEM, isolated small particles (presumably correlated to aluminium oxides) exist at the regrown/processed interface of the set 1 samples, but no other defects such as dislocation are seen. Impurities and defects are mainly caused by the high reactivity of AlGaAs during ECR plasma etching.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 2688-2693 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Cadmium sulfide (CdS) and zinc sulfide (ZnS), direct gap semiconductors with room temperature band-gap energy of 2.42 and 3.66 eV, respectively, form a continuous series of solid solutions (Cd1−xZnxS). The band-gap energy of Cd1−xZnxS can be tailored in the range of the binary band gaps. In this work, polycrystalline films of Cd1−xZnxS have been deposited on glass, SnO2:F/glass, and ZnO:F/glass substrates by the reaction of dimethylcadmium (DMCd), diethlyzinc (DEZn), and propyl mercaptan (PM) in a hydrogen atmosphere. The deposition rate and properties of Cd1−xZnxS films depend on the substrate temperature and the composition and flow rate of the reaction mixture. The deposition rate of Cd1−xZnxS films has been measured at 375 and 425 °C as a function of the DMCd/DEZn molar ratio in the reaction mixture. Without intentional doping, the deposited films are of high lateral resistivity, and the resistivity increases with increasing ZnS concentration. The electrical resistivity of the deposited films can be reduced by using octyl chloride or trimethylaluminum as a dopant. The effects of DMCd/DEZn and (DMCd+DEZn)/PM molar ratios on the optical and electrical properties of Cd1−xZnxTe films have been investigated. Thin film heterojunctions have been prepared by the successive in situ metal organic chemical vapor deposition of Cd0.7Zn0.3S (Eg∼2.8 eV), an absorber, and the ohmic contact on a ZnO:F/glass substrate, and their electrical and photovoltaic properties characterized.
    Materialart: Digitale Medien
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  • 4
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: InGaAsP/InP single-quantum well and multiquantum-well (MQW) structures have been successfully grown by low-pressure metalorganic chemical vapor deposition (LP-MOCVD). The quantum wells grown consist of 1.3- and 1.5-μm composition InGaAsP, with barriers of InP. Layer thicknesses vary from 18 to 1300 A(ring) for the various structures grown. Analysis of these structures by low-temperature photoluminescence reveals distinct, sharp luminescent peaks, with half-widths from 4.8 to 13 meV. Cross-sectional transmission electron microscopy (XTEM) and Auger spectroscopy of the quantum-well structures reveals extremely sharp interfaces and homogeneous composition, demonstrating the feasibility of LP-MOCVD for the growth of very thin epitaxial layers. This preliminary data indicates that the growth of MQW structures for the next generation of laser diodes (i.e., MQW-distributed-feedback lasers), with monolayer interfacial abruptness, is possible by LP-MOCVD.
    Materialart: Digitale Medien
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  • 5
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The temperature dependence of the resistance in the Pt(60 nm)/Ti(50 nm) nonalloyed ohmic contacts to p-InAs (Zn doped 1×1018 to 1×1019 cm−3 ) induced by rapid thermal processing in the temperature range of 300–600 °C was studied. The ohmic nature of these contacts was attributed to both the low metal-semiconductor interfacial barriers and to the heavily doped semiconductor contacting layers. A phenomenological model was used to fit the measured temperature dependence contact resistance. The results indicated conversion from thermionic emission as the dominant carriers transport mechanism across the interfacial barrier for the as-deposited sample to a combination of thermionic and field emission mechanism for the heat-treated samples.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 4095-4097 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We have investigated the doping incorporation and activation of InP growth using metalorganic chemical vapor deposition on 〈100(approximately-greater-than), 〈311(approximately-greater-than)B, and 〈110(approximately-greater-than) InP substrates. Effects of orientation, growth temperature, and V/III fluxes were studied. The dopants used were Zn from dimethylzinc [(CH3)2Zn] and diethylzinc [(C2H5)2Zn], S from hydrogen sulfide [H2S], Si from silane [SiH4], and Sn from tetraethyltin [(C2H5)4Sn]. The incorporation and activation of the p-type dopant Zn are elevated on the 〈311(approximately-greater-than)B and 〈110(approximately-greater-than) planes, while the incorporation is suppressed for the n-type dopants (S, Si, and Sn). The n-type dopant Sn has similar incorporation and activation on the various substrate orientations studied. Anomalous Zn doping on the higher order planes 〈311(approximately-greater-than)B and 〈110(approximately-greater-than) lead to the Zn incorporation exceeding the solubility limit in InP. Incorporated Zn levels as high as 1.0×1019 cm−3 were measured, and the corresponding activated Zn level was as high as 5.4×1018 cm−3 on a 〈110(approximately-greater-than) InP substrate. Interdiffusion of the p-type dopant Zn into the S-doped n-type InP substrate is inhibited by a high S-doping level and segregates at the substrate–epilayer interface. If the S-doping level is lower than the Zn concentration, then Zn diffuses deep into the substrate at a uniform level.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 71 (1992), S. 5635-5640 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Cadmium telluride (CdTe) and zinc telluride (ZnTe), direct gap semiconductors with room-temperature band gap energies of 1.45 and 2.25 eV, respectively, form a continuous series of solid solutions (Cd1−xZnxTe). The band gap energy of Cd1−xZnxTe can be tailored in the 1.45–2.25 eV range. Cd1−xZnxTe with band gap energy of 1.65–1.75 eV is suitable as the upper member of a two-cell tandem structure for the photovoltaic conversion of solar energy. In this work, polycrystalline films of Cd1−xZnxTe have been deposited on glass, CdS/SnO2:F/glass, and Cd1−xZnxS/SnO2:F/glass substrates at 400 °C by the reaction of dimethylcadmium (DMCd), diethlyzinc (DEZn), and diisopropyltellurium (DIPTe) in a hydrogen atmosphere. The composition of Cd1−xZnxTe films determined by wavelength dispersive spectroscopy and x-ray diffraction has been correlated with the band gap energy deduced from the junction photovoltage spectroscopy and optical transmission. The structural and electrical properties of Cd0.7Zn0.3Te (band gap energy 1.70 eV) films have been evaluated. Thin film Cd0.7Zn0.3Te/CdS and Cd0.7Zn0.3Te/Cd0.7Zn0.3S heterojunctions have been prepared and characterized.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 7608-7612 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Cadmium telluride is a promising thin-film photovoltaic material as shown by the more than 10% efficient CdS/CdTe heterojunction solar cells. In this work, thin-film CdS/CdTe solar cells have been prepared using CdS films grown from an aqueous solution and p-CdTe films deposited by close-spaced sublimation (CSS). The properties of CdS films deposited from an ammonical solution of a Cd-salt, an ammonium salt, and thiourea have been controlled by optimizing the temperature and composition of the solution. The solution-grown CdS films have a high photoconductivity ratio, and its optical transmission is superior to that of vacuum evaporated CdS films. The properties of p-CdTe films deposited by CSS have been optimized by controlling the temperature and composition of the source material, and the substrate temperature. The properties of CdS/CdTe heterojunctions have been studied; junction photovoltage spectroscopy is used for the qualitative comparison of junction characteristics. Solar cells of 1-cm2 area with an AM 1.5 efficiency of 13.4% are reported.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1510-1520 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Various types of InP-based semiconductor lasers, Fabry–Perot (FP), and distributed feedback (DFB), in different wavelength regions of 1.3, 1.48, and 1.55 μm have been subjected to human-body-model electrostatic discharge (ESD) testing. The reverse V-I characteristics of these diode lasers were found to be generally most sensitive in detecting ESD damage than the forward characteristics (e.g., threshold current) of the laser. The laser ESD failure voltages were much lower for the reverse than the forward polarity and DFB lasers were found to be more vulnerable to ESD than FP lasers. The failure mechanism was found to be due to localized melting—a thermal effect—in both polarities of ESD testing. We also report the study of the latent ESD effects on the long-term aging rates of semiconductor lasers.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 630-632 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We have grown InGaAs quantum wells (QW), lattice matched to InP, with spatially modulated thickness along the [01¯1¯] direction of the crystal. Kinetic roughening alters the morphology of the underlying InP buffer layer and leads to the modulation of the well thickness. Photoluminescence (PL) emission reveals two distinct peaks, corresponding to excitons bound to well sections of different thicknesses. Comparison of PL spectra of 10 and 40 A(ring) QW samples at different temperatures clearly indicates carrier confinement in the thicker well section. This effect is potentially useful for the preparation of quantum wires.
    Materialart: Digitale Medien
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