ALBERT

Description: Biogeochemical parameters collected on RRS Discovery cruise DY080 in June 2017 through two mid-high latitude North Atlantic eddies. Includes macronutrient concentrations, dissolved iron and dissolved manganese, phytoplankton chlorophyll-a, particulate organic carbon and nitrogen, biogenic silicate, flow cytometry cell counts, temperature and salinity.

Description: Current velocities of the upper water column along the cruise track of R/V Meteor III cruise MET187 were collected by a vessel-mounted 38 kHz RDI Ocean Surveyor ADCP. The ADCP transducer was located at 5.0 m below the water line. The instrument was operated in narrowband mode (WM10) with a bin size of 16.00 m, a blanking distance of 16.00 m, and a total of 100 bins, covering the depth range between 37.0 m and 1621.0 m. Heading, pitch and roll data from the ship's motion reference unit and the navigation data from the Global Positioning systems were used by the data acquisition software VmDAS internally to convert ADCP velocities into earth coordinates. Measured velocities and bin-depth mapping were corrected due to occasional incorrect temperature measurements at the transducer that affected the sound velocity calculation. Corrected sound velocity values were derived using temperature measured by the ship's thermosalinograph. Single-ping data / ping ensembles were screened for bottom signals and, where appropriate, a bottom mask was manually processed. The ship's velocity was calculated from position fixes obtained by the Global Positioning System (GPS). Accuracy of the ADCP velocities mainly depends on the quality of the position fixes and the ship's heading data. Further errors stem from a misalignment of the transducer with the ship's centerline. Data post-processing included water track calibration of the misalignment angle (-44.8220° +/- 0.6351°) and scale factor (1.0046 +/- 0.0109) of the Ocean Surveyor signal. The velocity data were averaged in time using an average interval of 60 s. Velocity quality flagging is based on following threshold criteria: abs(UC) or abs(VC) 〉 1.5 m/s, rms(UC_z) or rms(VC_z) 〉 0.3.

Description: Current velocities of the upper water column along the cruise track of R/V Meteor III cruise MET187 were collected by a vessel-mounted 75 kHz RDI Workhorse Long Ranger ADCP. The ADCP transducer was located at 5.0 m below the water line. The instrument was operated in broadband mode (WM1) with two different configurations: (1 - corresponding to met_187_vmadcp_75khz_01.nc) bin size: 5.0 m, blanking distance: 2.0 m, number of bins: 128, vertical range: 12.0 m - 647.0 m; (2 - corresponding to met_187_vmadcp_75khz_0[2,3].nc) bin size: 8.0 m, blanking distance: 4.0 m, number of bins: 100, vertical range: 17.0 - 809.0 m. Heading, pitch and roll data from the ship's motion reference unit and the navigation data from the Global Positioning systems were used by the data acquisition software VmDAS internally to convert ADCP velocities into earth coordinates. Single-ping data / ping ensembles were screened for bottom signals and, where appropriate, a bottom mask was manually processed. The ship's velocity was calculated from position fixes obtained by the Global Positioning System (GPS). Accuracy of the ADCP velocities mainly depends on the quality of the position fixes and the ship's heading data. Further errors stem from a misalignment of the transducer with the ship's centerline. For technical reasons, the transducer was lifted from the moonpool on February 18th, 2023. Therefore, two separate calibrations were carried out: Data post-processing included water track calibration of the misalignment angle and scale factor of the Ocean Surveyor signal. For technical reasons, the transducer was lifted from the moonpool on February 18th, 2023. Therefore, two separate calibrations were carried out: prior February 18th, 2023 (corresponding to met_187_vmadcp_75khz_0[1,2].nc): misalignment angle of -41.8717° +/- 0.4333° (0.5755°), scale factor of 1.0001 +/- 0.0064 (0.0079); after February 18th, 2023 (corresponding to met_187_vmadcp_75khz_03.nc): misalignment angle of -41.8071° +/- 0.5600°, scale factor of 0.9971 +/- 0.0074. The velocity data were averaged in time using an average interval of 60 s. Velocity quality flagging is based on following threshold criteria: abs(UC) or abs(VC) 〉 1.5 m/s, rms(UC_z) or rms(VC_z) 〉 0.3.

Description: Underway temperature and salinity data was collected along the cruise track with two autonomous thermosalinograph (TSG) systems, each consisting of a SBE21 TSG together with a SBE38 Thermometer. Both systems worked independent from each other throughout the cruise. While temperature is taken at the water inlet in about 5 m depth, salinity is estimated within the interior TSG from conductivity and interior temperature. No correction against independent data was performed for temperature. Salinity was calibrated against independent water samples. Finally, TSG1 was chosen for publication. For details to all processing steps see Data Processing Report.

Description: Water clarity and color were observed during the RV METEOR cruise M187 (ReSEAt, 25.01.2023 - 04.03.2023, Walvis Bay, Namibia - Walvis Bay, Namibia) using a white Secchi disc with a diameter of 40 cm and a Forel-Ule color scale. The Secchi depth (SD) was recorded as a relative measure of water clarity at each in situ station during day time. At half SD the apparent color of the water above the submerged Secchi disc was determined using the Forel-Ule color scale. A Forel-Ule color scale is a classic tools used to differentiate the percieved color of water based on a scale from 1 (indigo blue) to 21 (cola brown). The measurements were conducted as recemmend in literature (Garaba and Zielinski, 2015; Wernand, 2011; Wernand and van der Woerd, 2010).

Description: Raw data acquired by position sensors on board RV METEOR during expedition M187 were processed to receive a validated master track which can be used as reference of further expedition data. During M187 the motion reference unit Kongsberg SeaTex AS MRU-5 combined with Kongsberg SeaTex AS Seapath 320 and two C and C Technologies GPS receivers C-NAV3050 were used as navigation sensors. Data were downloaded from DAVIS SHIP data base (https://dship.bsh.de) with a resolution of 1 sec. Processing and evaluation of the data is outlined in the data processing report. Processed data are provided as a master track with 1 sec resolution derived from the position sensors' data selected by priority and a generalized track with a reduced set of the most significant positions of the master track.

Description: Underway optical chlorophyll-a and turbidity data were collected along the cruise track with Sea-Bird Scientific ECO FLNTU sensors installed within two autonomous measurement systems, called self-cleaning monitoring boxes (SMBs). The SMBs measure alternatingly. While one box is measuring, the other one is being cleaned. At the beginning of the transect, the boxes switched to operation every three hours, later, while the ship is transecting the Pacific Gyre, the cleaning interval was changed to only every 24 hours. The water inlet for the SMBs is at about 4 m depth. The data were quality controlled and the chlorophyll-a data were additionally calibrated using discrete water samples. In situ chlorophyll-a samples were collected by the scientific party from Niskin bottles during CTD stations and underway using a tow fish. Chlorophyll-a of these samples was determined in the lab on board using a bench top fluorometer. Details on all quality control steps, the calibration, as well as a comparison to satellite data can be found in the data processing report. The resulting data set contains the original data and corresponding quality flags and, in case of chlorophyll-a, additionally the calibrated data plus quality flag. The data source is given through the name of the active SMB. The data set contains data during transect and station. We recommend to use ship's speed to filter for only transect data.

Description: Raw data acquired by position sensors on board RV METEOR during expedition M187 were processed to receive a validated master track which can be used as reference of further expedition data. During M187 the motion reference unit Kongsberg SeaTex AS MRU-5 combined with Kongsberg SeaTex AS Seapath 320 and two C and C Technologies GPS receivers C-NAV3050 were used as navigation sensors. Data were downloaded from DAVIS SHIP data base (https://dship.bsh.de) with a resolution of 1 sec. Processing and evaluation of the data is outlined in the data processing report. Processed data are provided as a master track with 1 sec resolution derived from the position sensors' data selected by priority and a generalized track with a reduced set of the most significant positions of the master track.

Description: Upwelling ocean currents associated with oxygen minimum zones (OMZs) supply nutrients fuelling intense marine productivity. Perturbations in the extent and intensity of OMZs are projected in the future, but it is currently uncertain how this will impact fluxes of redox‐sensitive trace metal micronutrients to the surface ocean. Here we report seawater concentrations of Fe, Mn, Co, Cd, and Ni alongside the redox indicator iodide/iodate in the Peruvian OMZ during the 2015 El Niño event. The El Niño drove atypical upwelling of oxygen‐enriched water over the Peruvian Shelf, resulting in oxidized iodine and strongly depleted Fe (II), total dissolved Fe, and reactive particulate Fe concentrations relative to non‐El Niño conditions. Observations of Fe were matched by the redox‐sensitive micronutrients Co and Mn, but not by non‐redox‐sensitive Cd and Ni. These observations demonstrate that oxygenation of OMZs significantly reduces water column inventories of redox‐sensitive micronutrients, with potential impacts on ocean productivity. Plain Language Summary Some trace metals, including iron, are essential micronutrients for phytoplankton growth. However, the solubility of iron is very low under oxygenated conditions. Consequently, restricted iron availability in oxygen‐rich seawater can limit phytoplankton growth in the ocean, including in the Eastern Tropical South Pacific. Under typical conditions, depleted oxygen on the South American continental shelf is generally thought to enhance iron supply to the ocean, fuelling phytoplankton productivity in overlying waters. However, the impact of changes in oxygenation, which are predicted to occur in the future, are not known. The 2015 El Niño event led to unusually high oxygen on the Peruvian shelf, offering a system‐scale test on how oxygen influences seawater iron concentrations. We show that El Niño‐driven oxygenation resulted in marked decreases in iron and other metals sensitive to oxygen (cobalt and manganese), whilst metals not sensitive to oxygen (cadmium and nickel) were unaffected. The measured reductions in iron may have led to decreased phytoplankton productivity.

Description: Climate change has led to a ~ 40% reduction in summer Arctic sea-ice cover extent since the 1970s. Resultant increases in light availability may enhance phytoplankton production. Direct evidence for factors currently constraining summertime phytoplankton growth in the Arctic region is however lacking. GEOTRACES cruise GN05 conducted a Fram Strait transect from Svalbard to the NE Greenland Shelf in summer 2016, sampling for bioessential trace metals (Fe, Co, Zn, Mn) and macronutrients (N, Si, P) at ~ 79°N. Five bioassay experiments were conducted to establish phytoplankton responses to additions of Fe, N, Fe + N and volcanic dust. Ambient nutrient concentrations suggested N and Fe were deficient in surface seawater relative to typical phytoplankton requirements. A west-to-east trend in the relative deficiency of N and Fe was apparent, with N becoming more deficient towards Greenland and Fe more deficient towards Svalbard. This aligned with phytoplankton responses in bioassay experiments, which showed greatest chlorophyll-a increases in + N treatment near Greenland and + N + Fe near Svalbard. Collectively these results suggest primary N limitation of phytoplankton growth throughout the study region, with conditions potentially approaching secondary Fe limitation in the eastern Fram Strait. We suggest that the supply of Atlantic-derived N and Arctic-derived Fe exerts a strong control on summertime nutrient stoichiometry and resultant limitation patterns across the Fram Strait region.