ALBERT

Description: Global deposits of concentrated phosphates, which are a necessary source for the production of phosphate fertilizers, are limited. These reserves keep getting thinner, and every day, large amounts of phosphorus end up in watercourses. In this study, we verified that modified biochar (saturated with FeCl3 solution and then neutralized with NaOH solution) can adsorb significant amounts of phosphorus from wastewater. Moreover, the agrochemical qualities of sludge water from a municipal wastewater treatment plant, struvite, phosphorus-saturated biochar, and iron(III) phosphate from a reused biochar filter were tested in this study. We determined the amount of mobile phosphorus as well as the amount of extractable phosphorus and its five fractions. It was found that modified biochar can hold one-third of the phosphorus amount contained in the commonly used agricultural fertilizer simple superphosphate (1 × 105 g of modified biochar captures up to 2.79 × 103 g of P). Moreover, plants can more easily access phosphorus biochar fractions than struvite, which is formed spontaneously during sludge management. The results of this research prove that the proposed method of recycling phosphorus from wastewater can be applied in technological practice.

Description: Organic farmers farming on arable land have often had, in addition to the cultivation of common species of cultivated crops (such as wheat, rye, triticale or potatoes), interest in the cultivation of marginal crops such as hulled wheat species (Einkorn, Emmer and Spelt wheat). The production of marginal cereals has seen significant developments in the European Union related to the development of the organic farming sector. Just the average annual organic production of spelt in the Czech Republic reached more than 9000 tons in 2018. The cultivation of these cereals requires post-harvest treatment in the special method of dehulling. The waste emerging after dehulling of spikelet (i.e., chaff) accounts for about 30% of the total amount of harvest and can be used as an alternative fuel material. When considering the energy utilization of this waste, it is also necessary to obtain information on the energy quality of the material, as well as environmental aspects linked to their life cycle. For evaluating the energy parameters, the higher and lower heating value, based on the elemental (CHNS) analysis, was determined. The environmental aspects were determinate according to the Life Cycle Assessment (LCA) methodology where the system boundary includes all the processes from cradle to farm gate, and the mass unit was chosen. The SimaPro v9.1.0.11 software and ReCiPe Midpoint (H) within the characterization model was used for the data expression. The results predict the energy potential of chaff about 50–90 TJ per year. The results of this study show that in some selected impact categories, 1 kg of chaff, as a potential fuel, represents a higher load on the environment than 1 kg of lignite, respectively potential energy gain (1 GJ) from the materials.