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  • Articles  (2)
  • Articles: DFG German National Licenses  (2)
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  • 1
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Abundant and diverse platinum-group minerals (PGM) occur throughout the Tertiary layered intrusion on Rum, Scotland. In this paper we document the distribution of PGM within the Eastern Layered Series (ELS) on Rum, which comprises 16 alternating units of olivine-dominant feldspathic peridotite grading to plagioclase-dominant allivalite. The PGM occur in six main chrome-spinel layers in the Eastern Layered Series and are clearly associated with minor concentrations of interstitial sulphides. Common PGM phases include: Pd–Cu alloys, Pt–Fe alloys, native Pt, laurite, moncheite, sperrylite, isomertiete, cooperite and braggite along with a large number of other less common arsenide, bismuthotelluride and sulphide phases. Analyses of the discrete chromitite layers yield up to ΣPGE + Au 2618 ppb. Although present throughout the 750-m-thick ELS, there are clear stratigraphical changes in the PGM assemblage. The presence of PGM in the ELS on Rum are interpreted as being caused by mantle melting associated with the proto-Icelandic `hot spot', followed by localised concentration because of the combined effects of magma mixing, sulphide-silicate liquid immiscibility and fractional crystallisation. Most of the PGM are magmatic in origin but some grains show evidence of hydrothermal alteration.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 14 (1979), S. 448-454 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: It is confirmed that the loss of HO· from the molecular ion of o-nitrotoluene involves exclusively a hydrogen from the methyl group. However, in higher homologues hydrogen atoms from non-benzylic sites are also implicated. With such compounds this fragmentation mode is shown not only by the ortho but, to a lesser extent, by the meta and para isomers as well. The proportion of the total ion current borne by the [M - 17]+ ion follows the order ortho 〉 meta 〉 para, which is attributed to substituent migration around the ring with a hydroxyl radical only being lost when the groups are on adjacent ring atoms. Other ions present in the spectra point to interaction between substituents to form a new heterocyclic ring.
    Additional Material: 7 Tab.
    Type of Medium: Electronic Resource
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