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  • 1
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A wavelength-dispersive x-ray fluorescence detector system has been developed that can be used to discriminate fluorescent photon energies for practically any incident flux. The system uses a Kumakhov polycapillary lens to collimate fluorescent photons from a sample. The collimated photons are transmitted to a crystal-counter combination on a stepping motor driven θ–2θ stage. The stage diffracts the photon wavelength of interest and a photon-counting or current-mode counter is used to measure the photons. The system had a resolution of less than 150 eV at 8 keV using the (200) reflection from an abraded and etched LiF crystal, and was easily able to discriminate between Zn Kα (8.620 keV) and Cu Kβ (8.905 keV) x rays emitted from a brass sample. The LiF (400) reflection had a resolution of approximately 50 eV, but with ten times less intensity. © 1995 American Institute of Physics.
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  • 2
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: In this paper we present the characterization by UV-VIS, Mössbauer, and EPR spectroscopy of [L2Fe2(μ-OH)3](ClO4)2⋅2CH3OH⋅2H2O, with L=N,N',N‘-trimethyl-1,4,7-triazacyclononane, a novel dimeric iron compound, which is shown to possess a central exchange-coupled delocalized-valence Fe(II/III) pair. Complete delocalization of the excess electron in the dimeric iron center is concluded from the indistinguishability of the two iron sites in Mössbauer spectroscopy. Mössbauer, EPR, and magnetic susceptibility data imply a system spin St =9/2 for the ground state. This finding is explained as being a consequence of the double-exchange interaction which is generated by the delocalized electron. Experimental values obtained from UV-VIS, Mössbauer, and EPR spectroscopy are for the double-exchange parameter B=1300 cm−1, the g factors gx,y =2.04 and gz =2.3, the parameters for zero-field splitting D=4 cm−1 and E≈0 cm−1, and for the hyperfine parameters ΔEQ =−2.14 mm s−1, Ax,y =−21.2 T, Az =−27 T, and δ=0.74 mm s−1. From our temperature-dependent studies we assign to the first excited state a spin-octet with an excitation energy Δ〉175 cm−1. From this value a lower bound of −235 cm−1 has been deduced for the exchange-coupling constant J. In the framework of a simplified description of the iron atoms by unperturbed 3d orbitals, the values of the A tensor components as well as the quadrupole splitting ΔEQ can be interpreted in a consistent manner by assuming the excess electron being delocalized over two dσ orbitals centered at the two iron sites of the dimer and directed along the iron–iron axis as the z direction.
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  • 3
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 57 (2001), S. 269-271 
    ISSN: 1399-0047
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: The acute myeloid leukaemia 1 (AML1) protein belongs to the Runx family of transcription factors and is crucial for haematopoietic development. The genes encoding Runx1 and its associated factor CBFβ are the most frequent targets for chromosomal rearrangements in acute human leukaemias. In addition, point mutations of Runx1 in acute leukaemias and in the familial platelet disorder FPD/AML cluster within the evolutionary conserved runt domain that binds both DNA and CBFβ. Here, the crystallization of the Runx1 runt domain is reported. Crystals belong to space groups C2 and R32 and diffract to 1.7 and 2.0 Å resolution, respectively.
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Advanced materials research Vol. 26-28 (Oct. 2007), p. 831-834 
    ISSN: 1662-8985
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The electrode(Ni-MWNTs) containing nickel(Ni) and multi-walled carbon nanotubes(MWNTs) was prepared by composite electrodeposit. Electrochemical hydrogen storage of theelectrode was studied. The result showed a high electrochemical discharging capacity of up to1361.1mA·h·g-1, which corresponds to a hydrogen storage capacity of 4.77Wt%(weight percent). Testof cyclic lifespan showed MWNTs had certain cyclic lifespan. Cyclic voltammetry tests showed thatMWNTs can store hydrogen in chemical form
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 364-366 (Dec. 2007), p. 1043-1047 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Based on the CROSSBAR network (CN) and the BANYAN network (BN), two newrearrangeable nonblocking constructions of extended BANYAN network (EBN) are proposed forimplementing 8×8 optical matrix switch. The interconnection characteristics of these two types ofrearrangeable nonblocking EBN were studied, and the logic program for driving switching unitswas provided. The calculated insertion loss was 3.3 dB for 8×8 optical matrix switch. Silicawaveguide 8×8 matrix optical switch was designed and fabricated according to the calculatedresults. The silica waveguide propagation loss of 0.1dB/cm and waveguide-fiber coupling loss of0.5dB/point were measured. With the fabricated 8×8 matrix optical switch, optical insertion loss of4.6 dB, cross-talk of -38 dB, polarization dependent loss of 0.4 dB, averaged switching power of1.6 W, and switching time of 1 ms were achieved. A basic agreement between experimental resultsand theoretical calculated values was achieved
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of inclusion phenomena and macrocyclic chemistry 26 (1996), S. 175-183 
    ISSN: 1573-1111
    Keywords: β-CD ; enthalpy-entropy compensation ; inclusion complex ; naphthalene derivatives ; substituent effect
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The inclusion complexation ofβ-CD with 1-substituted naphthalenes has been investigated by fluorescence spectroscopy. It was observed that the association constants were influenced by the molar refraction (R m), hydrophobic constant (π x ), and Hammett constant (σ x ) of substituents in the guest compounds. The thermodynamic parameters ΔG0, ΔH 0, and ΔS 0 determined by measuring the temperature-dependentK a values shows that inclusion complex formation is enthalpy driven. The results are discussed in terms of enthalpy-entropy compensation.
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  • 8
    ISSN: 1573-1111
    Keywords: β-cyclodextrin ; inclusion complexation ; molecular dynamics ; phenothiazine derivatives
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Inclusion complexation of β-cyclodextrin (β-CD) with N-phenylphenothiazine ( 1), N-benzylphenothiazine ( 2) and N-phenethylphenothiazine ( 3) has been studied by means of UV-vis spectroscopy and molecular dynamics simulations. The association constants (Ka) were determined to be 126, 312 and 211 dm3/mol for inclusion of β-CD with 1, 2 and 3, respectively. It shows that the Ka values are affected by the substituents of the guest compounds. The structures of the complexes and the conformation of the guest compounds bound by β-CD in the complex have been discussed.
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  • 9
    ISSN: 1572-9788
    Keywords: debranching enzyme ; microsatellite ; malting quality ; marker-assisted selection
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A DNA fragment containing the exons 16, 17 and intron 16 of the limit dextrinase gene was cloned using a 654 bp cDNA as probe. Intron 16 contained a simple sequence repeat (microsatellite). PCR primers were designed to amplify that microsatellite. Using these primers, the limit dextrinase gene was mapped to the short arm of chromosome 1 (7H) using 150 DH lines from the Steptoe × Morex mapping population. This gene co-segregated with the RFLP marker ABC154A. QTLs for malt extract, α-amylase activity, diastatic power and fine-coarse difference previously mapped in the North American Barley Genome Mapping Project have been located in this chromosome region. Five limit dextrinase alleles were detected in 31 barley cultivars with a PIC of 0.75. Ten different alleles/genes were identified in 23 uncultivated Hordeum species or subspecies using these microsatellite primers. The primers also amplified one fragment from wheat and two from oat. This microsatellite should be useful for marker-assisted selection for malting quality.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 43 (1998), S. 69-91 
    ISSN: 0029-5981
    Keywords: computational fracture ; dual path integral ; bound estimation ; quasi-equilibrium approach ; Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Based on the energy foundation of the path-independent integral in non-linear fracture mechanics, I* integral as the dual form of Rice's J is presented, it is also path-independent and is equivalent to J in value but it relates to the complementary energy. It is proved that, in numerical implementation, the path independence of J and I* can be ensured by using the assumed displacement finite elements and the assumed stress finite elements, respectively. Regarding the bounds of crack parameters, it is demonstrated that the lower bound of J can be estimated by the displacement compatible elements, and the upper bound of I* can be estimated by the stress equilibrium elements. In view of the difficulties in formulating stress equilibrium model, instead of it, a quasi-equilibrium model is proposed, which makes hybrid stress elements be able to estimate the bound of I*, and do not lose the characteristics of stiffness formulation. Two four-node plane elements are suggested; of them, the incompatible one can be used in incompressible/fully plastic fracture analysis, and the penalty-equilibrium one can be implemented to estimate the bound of I*. Furthermore, an incremental formulation is developed for I*, and can be extended into the calculations of ductile fracture under monotonic loading. For attestation, quite a number of numerical experiments is carried out, and some significant results are offered. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 18 Ill.
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