Publication Date:
2018
Description:
〈span〉Oxygen and iron isotope variations have been investigated in three compositionally distinct garnet samples to assess natural variations and search for suitable reference material. We report 〈span〉in situ〈/span〉 major, trace element and O isotope analyses for mantle-derived garnet xenocrysts from Kakanui, New Zealand, as well as magmatic and hydrothermal garnets (skarn) from two different localities in Erongo, Namibia. The 〈span〉in situ〈/span〉 analyses are complemented by bulk mineral separate Fe isotope analyses for all samples and CO〈sub〉2〈/sub〉 laser fluorination oxygen isotope analysis for Kakanui garnet. Mantle-derived pyrope-rich garnet megacrysts from Kakanui are chemically homogeneous in major and trace elements, and in O isotopes, (δ〈sup〉18〈/sup〉O〈sub〉VSMOW〈/sub〉 = 5.67 ± 0.02‰). Magmatic garnet from Erongo, Namibia, is rich in Mn and Fe〈sup〉2+〈/sup〉 and very poor in Ca showing minor variations along the almandine–spessartine join [(Fe,Mn)〈sub〉3〈/sub〉Al〈sub〉2〈/sub〉Si〈sub〉3〈/sub〉O〈sub〉12〈/sub〉]. Although rare earth elements vary over one order of magnitude, no resolvable O isotope zoning is observed (δ〈sup〉18〈/sup〉O = 9.3 ± 0.3‰, 1σ). Hydrothermal garnet from Namibia is rich in Ca and Fe〈sup〉3+〈/sup〉 and shows strong zonation along the andradite–grossular join [Ca〈sub〉3〈/sub〉(Fe〈sup〉3+〈/sup〉,Al)〈sub〉2〈/sub〉Si〈sub〉3〈/sub〉O〈sub〉12〈/sub〉] with a considerable spread in trace-element contents, accompanied by a limited, but resolvable, spread in O isotopes values between cores (8.3 ± 0.3‰, 1σ) and rims (7.4 ± 0.3‰, 1σ). Iron isotopes (expressed as δ〈sup〉57〈/sup〉Fe〈sub〉IRMM-014〈/sub〉) within bulk garnet separates are heterogeneous in both crustal garnet from Erongo with a large spread ranging from −0.15 to +0.30‰ in igneous garnet and from +0.4 to +1.1‰ in hydrothermal garnet. Igneous garnet from Kakanui are homogeneous with an average δ〈sup〉57〈/sup〉Fe〈sub〉IRMM-014〈/sub〉 of +0.09 ± 0.01, 1σ. The Fe〈sup〉3+〈/sup〉-dominated andradite shows very heavy Fe isotopes, suggesting a link between preferential ferric iron incorporation into garnet and Fe isotope signatures. Combined O and Fe isotope analyses in garnet can provide potentially important insights into the nature of parental medium from which the garnet forms (based on O isotopes) and associated petrogenetic processes (〈span〉e.g.〈/span〉, redox conditions based on Fe isotopes), though more systematic studies are required to further assess these proxies in natural systems. Finally, we propose that Kakanui garnet might represent a suitable reference material for both, O and Fe isotope analyses.〈/span〉
Print ISSN:
0935-1221
Electronic ISSN:
1617-4011
Topics:
Geosciences
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