ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The gas-phase reaction products of the OH radical with 2-ethoxyethyl acetate (EEA, CH3C(O)OCH2CH2OCH2CH3) have been investigated. 1,2-Ethanediol acetate formate (EAF, CH3C(O)OCH2CH2OC(O)H) and ethyl formate (EF, HC(O)OCH2CH3) were identified as the two main products. A third product, ethylene glycol diacetate (EGD, CH3C(O)OCH2CH2OC(O)CH3), was also observed. EAF, EF, and EGD formation yields were determined to be 0.37 ± 0.03 and 0.328 ± 0.018 and 0.040 ± 0.005, respectively. Proposed reaction mechanisms are discussed and compared with these data. © 1996 John Wiley & Sons, Inc.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.1
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