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  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 51 (1987), S. 2164-2166 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have fabricated thin films of YBa2Cu3Ox by dc triode sputtering from two metallic targets. Post-annealing in pure O2 after sputtering resulted in superconducting films with a Tc onset as high as 89 K and a midpoint Tc of 75 K. We report preliminary results of films deposited on sapphire, MgO and sol-gel coatings of ZrO2 on sapphire, with and without buffer layers of Ag. The chemical and physical structures of these films were analyzed by using several x-ray diffraction techniques and Rutherford backscattering spectroscopy.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 76 (1972), S. 2317-2325 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry 57 (1965), S. 19-31 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 108 (1998), S. 1094-1102 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We consider nucleation of crystalline phase in a glass-forming melt which is quenched at some arbitrary rate, S, and then reheated at some other (typically smaller) rate, H. In conventional (steady-state) approaches it is assumed that the nucleation rate is a function of temperature only, so that the number of nucleated crystallites is proportional to 1/S+1/H. We demonstrate, however, that in general the nucleation rate depends on the quench/heating rate and that there exists an S- and H-dependent temperature region which effectively does not contribute to nucleation, so that the aforementioned scaling does not hold. An expression for the non-steady-state nucleation rate is derived analytically. In certain cases, the number of nucleated crystallites can be reduced by orders of magnitude compared to the steady-state predictions. The results are tested against numerically exact data obtained from the Turnbull–Fisher nucleation model. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 109 (1998), S. 186-195 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: An analytical description of devitrification kinetics induced by time-dependent nucleation and growth of crystallites during a quench-heating cycle is proposed. Relevant experimental situations include differential thermal analysis (DTA) or differential scanning calorimetry (DSC). The proposed description involves very few assumptions regarding the temperature dependence of various kinetic parameters, but rather employs measured values of growth rates. It is shown that the conventional description of nucleation based on the steady-state approximation, as a rule, is inapplicable for the description of the DTA/DSC experiment for experimentally reasonable quench/heating rates. The latter is confirmed by the analysis of available experimental data on o-terphenyl and lithium disilicate. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 5 (1972), S. 216-221 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: A small-angle X-ray scattering study of glassy GeO2 is reported. Data were obtained from 4π sin&thgr;/λ = 0.05 to 2.0 using a Kratky camera. The SAXS intensity decreased monotonically with decreasing angle from the main diffraction peak, and was not noticeably changed by hydrofluoric acid surface treatment or various annealing treatments. The intensity scattered at the smallest angle was 49±2.5 e.u. molec−1. Extrapolated to zero angle, the intensity corresponds to root-mean-square density fluctuations of 10−12 V−1/2 cm−3/2, a value close to that expected from the thermodynamic fluctuation theory of liquids. A parallel study of fused silica has indicated mean-square density fluctuations similar to those found in GeO2. The results are taken as evidence contrary to representations of structure based on specific arrays differing significantly from the interconnecting material.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Earth, moon and planets 13 (1975), S. 277-284 
    ISSN: 1573-0794
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The process of breccia formation by viscous sintering in the absence of pressure, advanced forcefully by Simonds (1973), is examined in detail. The limitations on the standard model for such sintering are considered. The competing process of crystallization is analyzed kinetically in terms of time-temperature-transformation curves corresponding to various degrees of crystallinity. The analysis is applied to Lunar Composition 15418 to illustrate the approach. The results indicate that close constraints can be placed on the thermal histories of lunar breccias, particularly breccias with modest degrees of crystallinity, from microstructural observations and kinetic measurements.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 8 (1997), S. 953-958 
    ISSN: 1573-4846
    Keywords: laser dyes ; pyrromethene-BF2 complexes ; photostability ; Polyceram ; solid-state laser
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Polyceram materials are attractive hosts for laser dyes because they can have high optical transparencies, high laser damage thresholds, and the ability to tailor optical properties by varying the composition and synthetic routes. Pyrromethene 567 has been successfully incorporated within silica: polydimethylsiloxane (PDMS) Polycerams to obtain polishable, crack-free, transparent monoliths using the sol-gel process. Fluorescence photostability was measured by pumping with aQ-switched, frequency doubled Nd: YAG laser (532 nm) at a pulse rate of 10 Hz. Fluorescence intensity dropped to 50% after approximately 50,000 pulses at a fluence of 0.10 J/cm2. UV degradation studies were performed on Polycerams with different polymer contents, and the absorption photostability is related to the solubility and type of caging of the dye.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 8 (1997), S. 973-978 
    ISSN: 1573-4846
    Keywords: silylated dyes ; laser dyes ; Polyceram ; photostability ; solid-state dye laser
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Numerous silylated coumarin dyes have been incorporated within silica: polydimethylsiloxane Polyceram hosts using the sol-gel process to form crack-free, polishable monoliths. The use of silylated laser dyes allows for covalently bonding the laser dyes to their hosts. Photostability of the samples was evaluated by measuring the decrease in the dye absorption in the Polyceram upon ultraviolet lamp exposure and by monitoring the fluorescence intensity as function of pump pulses from a N2 laser at 337 nm. Both methods showed a significant improvement in photo- and thermal-stability of the silylated dye Polyceram compared to that of the unsilylated dye Polyceram at a dye: Si mole ratio of 10−4:1. The improved stability is attributed to the immobilization and higher degree of caging of the silylated dye Polyceram with respect to the unsilylated dye Polyceram.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 8 (1997), S. 1083-1091 
    ISSN: 1573-4846
    Keywords: coatings ; powders ; films ; applications ; optical
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract This paper addresses the future prospects for sol-gel processing. It includes responses from nearly two dozen leading practitioners of the sol-gel art, who were kind enough to answer a questionnaire about the present state and future directions of the field. Overall, the prospects appear quite bright; but achievement of anything like the full potential of the method will require greatly increased interaction between sol-gel specialists and device technologists.
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