ISSN:
0009-2940
Keywords:
Silene
;
Oxidation
;
Molecular oxygen
;
Matrix isolation
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The thermal oxidation of 1,1,2-trimethylsilene (1) has been investigated in O2-doped argon matrices. The oxidation proceeds rapidly at temperatures below 40 K, and two principal oxidation products have been identified as dimethylvinylsilyl hydroperoxide (6) and dimethylvinyloxysilanol (7). The mechanism leading to these products is discussed.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921251230
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