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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 4003-4009 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The growth of GaS films on GaAs(001) surfaces by using thermal evaporation of layered-compound GaS has been investigated by Auger electron spectroscopy, low-energy electron-loss spectroscopy (LEELS), x-ray photoemission spectroscopy (XPS), and atomic force microscopy (AFM) as a function of deposition temperature. The LEELS spectrum of the films grown at lower temperatures (≤400 °C) resembles that of a GaS single crystal, whereas that of the films grown at 450 °C reveals that GaAs surface was terminated by Ga2S3 layer. XPS spectra suggest that after annealing at 500 °C, S atoms moved from As atoms to Ga atoms to form stable Ga–S bonds at the interface and As–S bonds are observed to be less stable. The band discontinuity at the GaS/GaAs(001) interface estimated by XPS showed the straddling-type I band alignment. Surface morphology of the films studied by AFM reveals the layer-by-layer initial growth of GaS. © 1999 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 202-208 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Short-period (Sim/Gen)N superlattices (SSLs) are grown step by step on a Si(001) substrates by solid source molecular beam epitaxy. Using the step-graded SSLs as buffer layers, 2000 Å uniform Si0.75Ge0.25 alloy layers are grown on the same substrates. The growth temperature of the SSLs and uniform layers is 500 °C. In the SSLs layers, m and n are the number of monolayers of Si and Ge, respectively. N is the period of (Sim/Gen) bilayers. The samples grown are characterized by x-ray diffraction, atomic force microscopy (AFM), and transmission electron microscopy (TEM) as a function of the step number of SSL layers. The SSLs show very smooth surfaces [the root-mean-square (rms) surface roughness is between 7 and 12 Å]. A dramatic decrease in roughness is observed in the uniform Si0.75Ge0.25 alloy layers, when even a one-step SSL is used as a buffer layer. A noticeable increase in rms roughness is seen in both SSL and alloy layers when the number of Ge monolayers is changed from one to two. AFM observation shows that the rms surface roughness behavior of the SSLs is reflected to their corresponding top alloy layers. The residual strains in alloy layers are considerably lower, with a maximum relaxation rate of about 80% for the sample with a seven-step SSL buffer. Cross-sectional TEM images show that strained SSL buffer layers effectively deflect threading dislocations in the substrate or confine the dislocations in the SSL buffer layers. © 2001 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 724-729 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Heteroepitaxial growth of InSb was performed on Si(111)–(7×7) and Si(111)–In(4×1) surface phases over a wide temperature range, by optimizing the growth rate and substrate temperature. When the heteroepitaxy was performed on the Si(111)–In(4×1) surface, the In(4×1) reconstruction modified the growth process depending on the growth temperature. At low temperatures, the In(4×1) reconstruction contributes mildly to the growth, and as the growth temperature increases, it starts degrading the quality of the films. For temperatures above 300 °C, the In(4×1) reconstruction virtually destroys the growth. In the present article, we illustrate this behavior using the growth of InSb on both Si(111)–(7×7) and Si(111)–In(4×1) surfaces at 210, 250, and 300 °C. Based on reflection high-energy electron diffraction observations, we discuss the initial stages of growth. A model for the interface formation is proposed based on our earlier results suggesting the temperature-dependent modification of In-induced surface phases on Si(001) and Si(111) surfaces during Sb deposition. © 2000 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 8759-8765 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Residual strain, surface roughness, and dislocations of Si1−xGex alloy layers grown by molecular beam epitaxy on Si(001) substrates at 550 °C have been characterized by x-ray diffraction, atomic force microscopy, and cross-sectional transmission electron microscopy (XTEM). Two kinds of samples were grown. One is a series of Si1−xGex alloy layers with x≤0.3 and a thickness of 5000 Å directly grown on Si(001) substrates, and the other is a series of Si0.7Ge0.3 alloy layers with a thickness of 2000 Å grown on Si(001) via compositionally graded Si1−yGey buffer layers (0≤y≤x). The Ge grading rate gr in the buffer layer, defined by gr% Ge/μm, ranged from 22 to 76. In the case of direct growth, the surface morphology changes from a wavy ripple pattern to a cross-hatch pattern with increase in x, and islandlike patterns appear at x=0.3. The residual strain decreases with increase in x, whereas the surface roughness increases with x. In the case of Si0.7Ge0.3 alloy layers grown with buffer layers, the surfaces of all samples display cross-hatch pattern. The surface roughness is highest for a grading rate of about 35, and it decreases for both lower and higher grading rates. The residual strain also shows a similar dependence on the grading rate. XTEM images are correlated to the residual strain and surface roughness. © 2000 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 3213-3217 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have studied the formation of a high-quality SrTiO3 (STO) film on a Si surface which is an appropriate buffer film for fabricating high-Tc superconductor devices on Si by molecular beam epitaxy. The STO films with thicknesses of 1300–6700 Å are grown on a SrO buffer layer with a thickness of 100 Å on Si(001)-2×1 in ∼10−8 Torr. The growth temperatures for the STO films and SrO layer are 500 and 400 °C, respectively. The as-grown STO films are insufficiently oxidized regarding the Ti–O bond which is confirmed by the observation of x-ray photoemission spectroscopy, although in situ reflection high-energy electron diffraction spectroscopy and ex situ x-ray diffraction (XRD) reveal a high-quality crystalline structure. The in situ postannealing for the as-grown STO films is performed at 500–900 °C for 60 min in an oxygen atmosphere of 1×10−6 Torr. The heat treatment promotes the oxidation of STO films and results in a high resistivity of 109–1011 Ω cm and a dielectric constant of 130 at 100 kHz at room temperature. The films consist of large grains with 150–200 nm diameter on the surface in the image of atomic force microscopy. The heat treatment does not prominently affect the crystallinity of STO films in the XRD patterns. © 1999 American Institute of Physics.
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  • 6
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Real-time measurements of GexSi1−x/Si(001) composition and segregation dynamics in Sn/Si(001) in molecular beam epitaxy are demonstrated using parallel detection reflection electron energy loss spectroscopy. Parallel detection enables quantitative acquisition of low-loss spectra in a time of 〈500 μs and surface composition determination in GexSi1−x/Si(001) via Ge L2,3 core loss analysis to a precision of approximately 2% in time of order 1 s. Segregation and trapping kinetics of monolayer thickness Sn films during Si epitaxy on Sn-covered Si(100) has also been studied using the Sn M4,5 core loss. © 1997 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Surface Science 222 (1989), S. 332-342 
    ISSN: 0039-6028
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 8
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Surface Science 222 (1989), S. 343-350 
    ISSN: 0039-6028
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 9
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Surface Science Letters 222 (1989), S. A551 
    ISSN: 0167-2584
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Thin Solid Films 247 (1994), S. 134-139 
    ISSN: 0040-6090
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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