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  • 1
    Publication Date: 2020-12-03
    Description: A study of the He isotopic ratios of fluid inclusions in olivine and pyroxene from the Roman Comagmatic Province (RCP),Italy, is presented together with 87Sr/86Sr isotope compositions of the whole rock or pyroxene phenocrysts. A clear covariation in He and Sr isotopes is apparent, with a strong northward increase in radiogenic He and Sr being evident. He and Sr isotopes ratios range from 3He/4He = 5.2 Ra and 87Sr/86Sr = 0.7056 in south Campania, to 3He/4He = 0.44 Ra and 87Sr/86Sr = 0.715905 in the northernmost Latium. Helium isotope ratios are significantly lower than MORB values and are among the lowest yet measured in subduction zone volcanism. The 3He/4He of olivine and pyroxene phenocryst-hosted volatiles appear to be little influenced by posteruptive processes and magma–crust interaction. The 3He/4He–87Sr/86Sr covariation is consistent with binary mixing between an asthenospheric mantle similar to HIMU ocean island basalts, and an enriched (radiogenic) mantle end member generated from subduction of the Ionian/Adriatic plate. The contribution of radiogenic He from metasomatic fluids and postmetasomatism radiogenic ingrowth in the wedge is strongly dependent on the initial He concentration of the mantle. Only when asthenosphere He concentrations are substantially lower than the MORB source mantle, and metasomatism occurred at the beginning of the subduction (f30 Ma), can ingrowth in the mantle wedge account for the 3He/4He of the most radiogenic basalts.
    Description: - European Social Fund - Scottish Universities - Carnegie Trust for the Universities of Scotland.
    Description: Published
    Description: 295–308
    Description: partially_open
    Keywords: Roman Comagmatic Province ; fluid inclusions ; helium ; strontium ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 516427 bytes
    Format: 539 bytes
    Format: application/pdf
    Format: text/html
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  • 2
    Publication Date: 2017-04-04
    Description: Helium isotope ratios of olivine and pyroxene phenocrysts from Plio-Quaternary volcanic rocks from Southern Italy (seven Eolian Islands, Mt. Vulture, Etna, Ustica, Pantelleria) range from 2.3 to 7.1 Ra. Importantly the phenocryst 3He/4He correlate well with whole rock Sr isotopic composition (0.70309-0.70711) reflecting the mixing of two sources. A significant contribution of He from crustal contamination is recorded only occasionally (e.g., pyroxenes from Vulcano). When merged with data from the Roman Comagmatic Province, a remarkably strong near-linear He-Sr isotope correlation is apparent. The general northward decrease in 3He/4He corresponds to an increase in 87Sr/86Sr (and decrease in 143Nd/144Nd and 206Pb/204Pb) that is due to increasing metasomatic enrichment of the mantle wedge via subduction of the Ionian-Adriatic plate. Calculations based on the ingrowth of 4He in the wedge and on the 4He content of the subducting crust show that mechanisms of enrichment in radiogenic He are effective only if the wedge is strongly depleted in He relative to best estimates of the depleted mantle. This can be accommodated if the process of metasomatism by the subduction fluids depletes the mantle wedge. The 3He/4He of Pantelleria, Etna, Iblei, Ustica, Alicudi and Filicudi basalts (7.0 ± 0.6 Ra) define the mantle composition least affected by subduction-related metasomatism. Although these volcanoes are from a variety of tectonic regimes (subduction-related, intraplate, rifting) their similarities suggest a common origin of geochemical features. Their characteristics are consistent with a HIMU-type mantle that is either younger than the Cook-Austral island end-member, or has a lower 238U/204Pb.
    Description: In press
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: open
    Keywords: Helium isotope ; Strontium isotope ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: manuscript
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  • 3
    Publication Date: 2017-04-04
    Description: Helium isotope ratios of olivine and pyroxene from Plio-Quaternary volcanic rocks from Southern Italy (each of the seven Eolian Islands, Mt. Vulture, Etna, Ustica, Pantelleria), range from 2.3 to 7.1 Ra. A good correlation emerges with the 3He/4He of fumarolic fluids. Importantly the phenocryst 3He/4He correlate with whole rock Sr isotopes (0.70309-0.70711) reflecting the mixing of two sources. Crustal contamination of magmatic He isotopes is recorded only occasionally (e.g., pyroxenes from Vulcano). The He isotope values of Pantelleria, Etna, Iblei, Ustica, Alicudi and Filicudi (7.0 ± 0.6 Ra) define the mantle composition least affected by subduction. That these characterise volcanoes from a variety of tectonic regimes (subduction-related, intraplate, rifting) suggest a common origin of geochemical features and are consistent with a HIMU-type mantle that is either younger than the Cook-Austral island end-member, or one with lower 238U/204Pb. When merged with data from the Roman Comagmatic Province (Latium and Campania), a remarkably strong He-Sr isotope correlation is apparent. The general northward decrease in 3He/4He corresponds to an increase in 87Sr/86Sr and decrease in 143Nd/144Nd and 206Pb/204Pb that is due to increasing metasomatic enrichment of the mantle wedge via subduction of the Ionian Adriatic plate since 30 Ma. Calculations based on the ingrowth of 4He in the wedge and on the 4He content of the subducting crust show that mechanisms of enrichment in radiogenic He are effective only if the wedge is strongly depleted in He relative to best estimates of the depleted mantle.
    Description: Published
    Description: Vienna, Austria
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: open
    Keywords: Geochemistry ; Helium ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 4
    Publication Date: 2017-04-04
    Description: Helium isotope ratios of olivine and pyroxene phenocrysts from Plio-Quaternary volcanic rocks from southern Italy (seven Aeolian Islands, Mt. Vulture, Etna, Ustica, and Pantelleria) range from 2.3 to 7.1 Ra. Importantly, the phenocryst 3He/4He correlate well with whole rock Sr isotopic composition (0.70309– 0.70711), reflecting the mixing of two sources. A significant contribution of He from crustal contamination is recorded only occasionally (e.g., pyroxenes from Vulcano). When merged with data from the Roman Comagmatic Province, a remarkably strong near-linear He-Sr isotope correlation is apparent. The general northward decrease in 3He/4He corresponds to an increase in 87Sr/86Sr (and a decrease in 143Nd/144Nd and 206Pb/204Pb) that is due to increasing metasomatic enrichment of the mantle wedge via subduction of the Ionian-Adriatic plate. Calculations based on the ingrowth of 4He in the wedge and on the 4He content of the subducting crust show that mechanisms of enrichment in radiogenic He are effective only if the wedge is strongly depleted in He relative to best estimates of the depleted mantle. This can be accommodated if the process of metasomatism by the subduction fluids depletes the mantle wedge. The 3He/4He of Pantelleria, Etna, Iblei, Ustica, Alicudi, and Filicudi basalts (7.0 ± 0.6 Ra) define the mantle composition least affected by subduction-related metasomatism. Although these volcanoes are from a variety of tectonic regimes (subduction-related, intraplate, rifting), their similarities suggest a common origin of geochemical features. Their characteristics are consistent with a HIMU-type mantle that either is younger than the Cook- Austral island end-member or has a lower 238U/204Pb.
    Description: Published
    Description: Q02001
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: helium ; strontium ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2022-06-14
    Description: The eastern flank of the Mount Etna stratovolcano is affected by extension and is slowly sliding eastward into the Ionian Sea. The Pernicana fault system forms the border of the northern part of this sliding area. It consists of three E-W–oriented fault sectors that are seismically active and characterized by earthquakes up to 4.7 in magnitude (M) capable of producing ground rupture and damage located mainly along the western and central sectors, and by continuous creep on the eastern sector. A new topographic study of the central sector of the Pernicana fault system shows an overall bell-shaped profile, with maximum scarp height of 35 m in the center of the sector, and two local minima that are probably due to the complex morphological relation between fault scarp and lava flows. We determined the ages of lava flows cut by the Pernicana fault system at 12 sites using cosmogenic 3He and 40Ar/39Ar techniques in order to determine the recent slip history of the fault. From the displacementage relations, we estimate an average throw rate of ~2.5 mm/yr over the last 15 k.y. The slip rate appears to have accelerated during the last 3.5 k.y., with displacement rates of up to ~15 mm/yr, whereas between 3.5 and 15 ka, the throw rate averaged ~1 mm/yr. This increase in slip rate resulted in significant changes in seismicity rates, for instance, decreasing the mean recurrence time of M ≥ 4.7 earthquakes from ~200 to ~20 yr. Based on empirical relationships, we attribute the variation in seismic activity on the Pernicana fault system to factors intrinsic to the system that are likely related to changes in the volcanic system. These internal factors could be fault interdependencies (such as those across the Taupo Rift, New Zealand) or they could represent interactions among magmatic, tectonic, and gravitational processes (e.g., Kīlauea volcano, Hawaii). Given their effect on earthquake recurrence intervals, these interactions need to be fully assessed in seismic hazard evaluations.
    Description: Published
    Description: 304-317
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: JCR Journal
    Description: open
    Keywords: Etna ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 7 (1968), S. 2673-2681 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 7 (1968), S. 1-7 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 1333-1337 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Electrochemical and spectroscopic measurements were used to characterize the electrochromic behavior of sputtered V2O5 films. In response to lithium intercalation, the fundamental optical absorption edge of V2O5 shifts to high energies by 0.20–0.31 eV as the lithium concentration increases from Li0.0V2O5 to Li0.86V2O5. There is a corresponding increase in the near-infrared absorption that exhibits Beer's law behavior at low lithium concentrations. The shift in absorption edge results in a large decrease in absorbance in the 350–450 nm wavelength range. This effect is most prevalent in thin films which exhibit a yellow to colorless optical modulation on lithium intercalation. The cathodic coloration in the near infrared is relatively weak with a maximum coloration efficiency of 35 cm2/C.
    Type of Medium: Electronic Resource
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