ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Liquid sulfur-olefinic reactions at 140°C forming crosslinked polysulfide polymers have been investigated. A systematic approach to the characterization and some structure-property studies on these new polymeric materials has been presented. The olefinic systems of interest are endo-and exo-dicyclopentadiene and an oligomeric alkenyl polysulfide. Equimolar S8-olefinic system copolymers are amorphous and they show no tendency for sulfur crystallization. A correlation has been drawn between chemical structure and glass transition temperature of the copolymers and terpolymers. Mechanical properties and, in particular, chemical stress relaxation of the crosslinked polysulfide polymers have been investigated.
Additional Material:
12 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1980.170180201
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