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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 20 (1974), S. 461-466 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A solution is given for unsteady state concentration profiles in an infinitely long composite cylinder resulting from a step-change in concentration in a large reservoir surrounding the cylinder. The composite cylinder consists of an inner cylinder with diffusivity D1 surrounded by a permeable tube with diffusivity D2 and has interfacial mass transfer resistances at the cylinder-tube and tube-reservoir interfaces. Numerical values are given for the first eight roots and various coefficients of the solution for physical properties typical of tubular (hollow fiber) membranes. These results can be used in the analysis of data from unsteady state mass transfer experiments to determine the permeability of homogeneous tubular membranes. A simple, approximate method for data analysis is suggested for the rapid estimation of the permeability of both homogeneous and asymmetric (skinned) tubular membranes.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 1192-1199 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental method is described for measuring the permeability of small tubular (hollow fiber) membranes by means of an unsteady state diffusion experiment. Permeability data obtained by this method are reported for experimental collagen and commercial cellulose acetate membranes for urea, sucrose, and polyethylene glycol (MW ∼ 4 000).
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 540-547 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Elongational flow experiments with viscous polymeric material were conducted at a constant elongation rate on a modified tensile testing machine. Steady elongational and shear viscosity data and elongational stress growth data are presented for an isobutylene-isoprene copolymer at 100°C. S-shaped elongational stress growth curves are reported for cis-1,4-polyisoprene at 80°C.The stresses necessary to maintain a cylindrical specimen in steady elongational flow are indicated by a calculation which includes the effects of inertia, gravity, and interfacial tension.Interrelations among several elongational flow material functions are given for a constitutive equation based on the theory of linear viscoelasticity.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 19 (1979), S. 849-857 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A dimensional analysis based on four parameters has been developed previously to predict injection pressure; clamp force, and bulk temperature for the injection molding of amorphous materials in center-gated disk-shaped cavities. In this paper geometric and semicrystalline-materials approximations are introduced and tested for extending the previous analysis to include multigated thin cavities and semicrystalline materials. The combination of these approximations and the previous analysis, known hereafter as the Radial Flow Method (RFM), greatly simplifies the analysis of mold filling. The geometric approximation, which is based on a simple model for the axial stress distribution in the cavity, is shown to give reasonable predictions when compared with experimental data and a numerical two-directional flow simulation for the filling of an off-center-gated rectangular cavity with acrylonitrilebutadiene-styrene copolymer (ABS). The semicrystallinematerials approximation, in which heat capacity and viscosity changes during crystallization are neglected, is shown to give good agreement with experimental data for the filling of a center-gated disk-shaped cavity with polypropylene. As an illustration, the Radial Flow Method is used to analyze the molding of a large, thin-wall automobile interior trim panel. The inlet melt temperature, mold-wall temperature, part thickness, injection rate, viscosity and gate locations are varied in a series of calculations to determine the relative effectiveness of these variables in lowering the injection pressure and Clamp force. The results obtained with the Radial Flow Method are in good agreement with those obtained by a finiteelement simulation of two-directional flow.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 577-582 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A graphical method based on dimensional analysis is presented for estimating the injection pressure and clamp force required for injection molding amorphous polymers to form disk-shaped parts with a constant wall thickness. A procedure is suggested for estimating clamp force when the projected area of the mold cavity is smaller than the surface area of one side of the molded part. The results reported here are based on a numerical simulation of a power-law fluid filling a cold mold at a constant injection rate. The dimensionless bulk temperature and the ratios of the nonisothermal injection pressure (clamp force) to the isothermal injection pressure (clamp force) are given as functions of the dimensionless cooling time τ, the Brinkman number Br which characterizes viscous heating, the power-law exponent n, and a dimensionless temperature β which includes the inlet melt and mold wall temperatures and the temperature coefficient for viscosity.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 233-238 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dimensional changes in complex profile extrusions are classified as overall size and local shape changes which can be related naturally and systematically to changes in operating conditions. The theoretical basis and supporting experimental data for simultaneous, independent control of certain classes of extrudate dimensions are presented for the following strategies: (1) size control by manipulating line speed relative to extruder output rate, (2) shape control by manipulating extrudate swell through adjustments in stock temperature, and (3) shape control by manipulating local die flow by adjusting the die temperature set point.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 12 (1978), S. 401-419 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Two experimental methods have been developed to characterize the pressure-driven flow of a liquid through the walls of single hollow-fiber membranes. In one method, the permeation rate is measured directly by following the air-water interface in a pressurized pipet connected to a hollow fiber which is sealed at one end. With the second method, the permeation rate is determined by tracking the descent of an air bubble inside a pressurized hollow fiber sealed at one end. Results obtained by the two experimental methods are in good agreement. Darcy's law is used to analyze the experimental data because the Darcy permeability constant, k, is an intrinsic property of the material. The membrane dimensions and the Darcy permeability constant for reconstituted collagen hollow fibers are shown to be quite sensitive to hydrogen ion concentration and ionic strength. A conceptual link between the Darcy permeability constant and the membrane microstructure is obtained by combining the aligned-rod structural model for reconstituted collagen proposed by Kramer with a hydrodynamic calculation due to Happel and electrical double-layer theory. On the average, the predictions of this model for volume fraction solids and microstructure dimensions are in reasonable agreement with experimental observations.
    Additional Material: 4 Ill.
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  • 8
    Publication Date: 1974-05-01
    Print ISSN: 0001-1541
    Electronic ISSN: 1547-5905
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley on behalf of American Institute of Chemical Engineers.
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  • 9
    Publication Date: 1972-05-01
    Print ISSN: 0001-1541
    Electronic ISSN: 1547-5905
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley on behalf of American Institute of Chemical Engineers.
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  • 10
    Publication Date: 1975-11-01
    Print ISSN: 0001-1541
    Electronic ISSN: 1547-5905
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley on behalf of American Institute of Chemical Engineers.
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