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  • 1
    Electronic Resource
    Electronic Resource
    Homolytic oxoalkylation of protonatedN-heteroaromatic compounds (1993)
    Springer
    Russian chemical bulletin 42 (1993), S. 1839-1843 
    Details
    ISSN: 1573-9171
    Keywords: homolytic oxoalkylation ; heteroaromatic bases ; lead tetraacetate ; manganese triacetate ; pyridine ; quinoline ; 1-methylcyclobutanol ; 1-methylcyclopentanol
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The oxoalkylation of pyridine, 2-methyl-, 4-methyl-, 2,4-dimethyl-, 2,6-dimethylpyridines, quinoline, 4-methylquinoline, isoquinoline, and pyrazine with oxoalkyl radicals generated from 1-methylcyclobutanol or 1-methylcyclopentanol under the action of Pb(OAc)4 or Mn(OAc)3 has been carried out. The reaction products are isomers with 2-(6)- and 4-positions of the oxoalkyl group in theN-heteroaromatic ring. The isomer ratios have been determined as a function of the structure of theN-heteroaromatic compound and the reaction conditions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00698999
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  • 2
    Electronic Resource
    Electronic Resource
    Electrochemical oxidative ring opening of 1-methylcyclobutanol (1996)
    Springer
    Russian chemical bulletin 45 (1996), S. 1246-1248 
    Details
    ISSN: 1573-9171
    Keywords: 1-methylcyclobutanol ; manganese(III) acetate ; electrochemical oxidation ; pentane-2-one ; 5-chloropentane-2-one ; β-cleavage
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The manganese(III) acetate-mediated electrooxidative ring opening of 1-methylcyclobutanol (1) in acetic acid affords pentane-2-one (2) as the major product. The reaction of 1-methylcyclobutanol with Mn(OAc)3-LiCl gives 5-chloropentane-2-one (4.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01431635
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    Paper (German National Licenses)
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