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  • 1
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 296 (1982), S. 729-731 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] We have previously described5'6 the microstructures in the spinel polymorph of (Mg,Fe)2SiO4 (ringwoodite) from the Ten-ham chondritic meteorite, and suggested that the defects (Fig. 1 in ref. 5) found in the spinel were due to the partial inversion of ringwoodite to the 0 -phase. The defects found ...
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Mineralogy and petrology 33 (1984), S. 187-202 
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Zusammenfassung 435 Körner aus Goldseifen im North Saskatchewan und im Athabasca-Fluß wurden einer detaillierten Untersuchung mit optischer Mikroskopie, energie-dispersiver Mikrosondenanalytik und Rasterelektronenmikroskopie unterzogen. In den meisten Körnern umgibt ein Rand mit hohem Feinheitsgrad einen Kern mit niedrigem Feinheitsgrad (dies führt zu beträchtlichen Schwankungen des Ag-Gehaltes innerhalb des einzelnen Kornes; im Extremfall 4,3%–46,1% Ag). Die Charakteristik der Ränder gibt Anlaß zu der Hypothese, daß das Silber dieser Ränder in situ herausgelöst worden ist, bevor die Körmer transportiert wurden; die während des Transportes auf die Körner einwirkenden Kräfte haben dann die poröse Textur, die durch das herauslösen des Silbers entstanden waren, weitgehend zerstört. Es findet sich keine Änderung des durchschnittlichen Ag-Gehaltes mit zunehmender Transportweite flußabwärts, solange nur Kömer aus einem Größenintervall betrachtet werden. Dies deutet ebenfalls darauf hin, daß der überwiegende Teil des Silbers vor dem Transport herausgelöst wurde. Man findet jedoch Unterschiede im durchschnittlichen Ag-Gehalt zwischen Körnern verschiedener Größe. Das Auftreten von mehreren bestimmten Werten-Clustern der Feinheitsgrade, die in Proben aus beiden Flüssen zu finden ist, legt nahe, daß Au zum größten Teil aus mehreren, spezifischen Ursprungsgesteinen in den westlich gelegenen Gebirgen (Omineca Geanticline) stammt. Eine glazigene Umverteilung von Gold aus verschiedenen Lokalitäten des Kanadischen Schildes erscheint weniger realistisch.
    Notes: Summary The detailed characteristics of 435 placer gold grains from the North Saskatchewan and Athabasca rivers have been investigated using a combination of optical microscopy, energy dispersive electron microprobe analysis and SEM techniques. Most grains show high-fineness rims surrounding lower-fineness cores (giving an extreme range of 4.3%–46.1% Ag within an individual grain). Characteristics of the rims lend support to the hypothesis that they are the products ofin situ leaching of silver followed by transport which largely destroys a spongy texture produced by the leaching. There is no change in the average Ag content of grains of any given size range with distance downstream, which also indicates that all significant leaching takes place before transportation. However, differences are apparent in the average Ag content with grain size. The clustering about certain values of fineness of the nuclei of grains which is seen in samples from both rivers, suggests that Au was largely derived from specific sources in the mountains (Omineca geanticline) to the west rather than redistributed from Shield localities during glaciation.
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 306 (1983), S. 172-173 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Most determinations of REE in chondritic phosphates4,5 do not discriminate between apatite and merrillite, owing to difficulty in separation. However, Ebihara and Honda2 attempted to utilize grain-size differences for this purpose (other physical properties being closely similar). Phosphate ...
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  • 4
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 204 (1964), S. 722-724 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] A SCENSION ISLAND (lat. 7 57' S., long. 14 22' W.) is situated in the South Atlantic Ocean and rises from the crest of the Mid- Atlantic Ridge. The island is roughly triangular in outline and some 36 square miles in area. High temperatures, low rainfall and persistent trade winds characterize the ...
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 3 (1974), S. 149-150 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Twenty-five new measurements of Kβ/Kα X-ray intensity ratios for elements in the atomic number range 20 to 30 confirm other recent evidence that the variation with atomic number in this region is much less than previously thought, but there is still some disagreement for atomic numbers above 27. A table of recommended values is given.
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 10 (1981), S. 198-202 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A procedure has been developed for the calculation of background corrections in wavelength-dispersive electron microprobe analysis which reduces data acquisition times and offers the possibility of greater accuracy and lower detection limits, especially when the number of peaks concerned is large. An empirical ‘normalized background’ in conjunction with a modified version of Kramers' law (as developed for energy-dispersive analysis) is used to calculate continuum intensity, enabling the background to be estimated for any wavelength from a single measured value. This approach is compatible with modern trends towards automation of data acquisition and processing.
    Additional Material: 7 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 4 (1975), S. 65-70 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A technique is outlined which use the electron microprobe to obtain X-ray absorption spectra, by photon absorption, in the long wavelength region. Spectra are presented for SiO, SiO2, rectorite, talc, vermiculite, V2O5, Cr2O3, Fe2O3, maghemite, Mylar and collodion. For all compounds the main absorption edge is near to 536 eV, which is significantly higher than core binding measured in ESCA studies. The transition metal oxides and organic films show a sharp absorption line near 531 eV in addition to the above edge. This absorption line is very close in energy to the anomalous peak observed in the oxygen K emission spectra when using KAP or other acid phthalate crystals and it seems likely that the two phenomena are associated.
    Additional Material: 4 Ill.
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  • 8
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Computer fitting techniques have been used to derive a new expression for the relationship between X-ray continuum intensity and atomic number for a range of electron acelerating potentials up to 25 kV, continuum energies up to 10 keV and average atomic numbers up to thirty. A practical approach to background corrections in energy dispersive electron microprobe analysis, which utilizes this expression, is outlined. The procedure should lead to significant improvements in both accuracy and detection limits in this method of X-ray analysis.
    Additional Material: 6 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 10 (1981), S. 78-81 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Oil film contamination of the Be window of a Si detector has been demonstrated using archival information on X-ray intensities from calibration standards acquired over a two and a half year period. Although cleaning the window with a solvent restores sensitivity for soft radiation, recontamination can be rapid unless a small heating device is placed close to the window. A mathematical correction is suggested which avoids significant analytical errors from the effect of any contamination which may be present. It can be applied automatically by data processing software using information from the calibration standard spectrum.
    Additional Material: 3 Ill.
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  • 10
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    Mineralogical Society of America
    Publication Date: 2013-03-30
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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