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  • 1
    ISSN: 1573-157X
    Keywords: Apennines-Central Italy ; earthquake chemistry-isotope chemistry ; fluids behaviour-seismicity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract After the earthquakes of September 26, 1997, that hit the Umbria-Marcheboundary (Apennine, Central Italy), with a maximum 6.0 Mw, aprogram of geochemical surveying together with a collection ofhydrogeological changes episodes was extended throughout theepicentre-area, taking the yearly period of the seismic sequence as a whole.After a first areal screening, the Bagni di Triponzo thermal spring wasselected for a discrete temporal monitoring (weekly and monthly basis),being the unique thermal spring throughout the epicentre area. This sitedeserves peculiar interest in deepening the knowledge about deep fluidscirculation changing during seismicity.Laboratory and on-field analyses included major, minor and trace elementsas well as dissolved gases (He, Ar, CH4, CO2, H2S,222Rn, NH4, As, Li, Fe, B, etc...) and selected isotopic ratios(C, H, O, He, Sr, Cl), meaningful from tectonic point of view.The chemistry and isotopic chemistry of the spring were fully outlined anddiscussed, pointing out the main process involving the thermal aquifer: thewater-rock interaction inside the Evaporite Triassic Basement (ETB),possibly involving also the Paleozoic Crystalline Basement. On theother hand, sudden and apparent geochemical and hydrogeologicalvariations during the seismic sequence ruled out an evolution in thewater-rock interaction processes. They occurred both at depth, i.e.,induced by fluid remobilization within the crust explained by the Coseismic Strain Model and by the Fault Valve Activity Model, and in the shallow part of the reservoir (i.e., meteoric watercontamination). A statistical multivariable analysis (Factor Analysis) wasaccomplished to better constrain the correlation between the paroxysmalphases of the seismic sequence and the observed trends and spike-likeanomalies. The groundwater variations was inferred to occur mainly insidethe ETB, from depth (1–2 km) up to surface, particularly in associationof the Sellano earthquake (14/10/1997) and of the seismic re-activationof the sequence at the end of March 1998 (Gualdo Tadino-Rigali andVerchiano areas). The lack of deeper input from below the ETB (slightsignature of PCB), as the lack of He mantle signature, during the seismicperiod as a whole, accounted for seismogenic fault segments rooted onlyin the crust. The results also provide useful information about theearthquake-related response mechanisms occurring at this site, thatrepresent the basic task for planning and managing the impendinghydro-geochemical network aimed at defining the relationships betweenseismic cycle, fluids and reliable earthquake forerunners.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2006
    Keywords: TF II ; Task Force II ; New tectonic causes of volcano failure
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  • 3
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    In:  Geological Society Special Publication 213: 53-62.
    Publication Date: 2003-01-01
    Description: Water diffusion experiments were performed on a trachytic melt from the Agnano-Monte Spina explosive eruption (Phlegrean Fields, South Italy). Experiments were run in a piston cylinder apparatus at 1 GPa pressure, at temperatures from 1373 to 1673 K and for durations of 0 to 255 s, using the diffusion-couple technique. Water concentration profiles were measured by Fourier transform infrared spectrometry. Water diffusion coefficients at different temperatures and water concentrations were calculated from the total water profiles, using the Boltzmann-Matano technique. Over the investigated range of temperatures and water concentrations, the diffusivity of water in potassic melts (Dwater), m2/s can be described by Arrhenius equations that can be generalized for water concentrations between 0.25 and 2 wt% as follows: [IMG]fd1.gif" ALT="Formula" BORDER="0"〉 where CH2O is the water concentration in wt%, R is 8.3145 (J K-1 mol.-1) and T is the temperature in Kelvin. Water diffusivities in trachytic melts were compared with water diffusivities in rhyolitic and basaltic melts. The activation energies for water diffusivity in trachyte and basalt are comparable, and higher than the haplogranitic melt. This results in a convergence of water diffusion coefficients in all melts at lower (magmatic) temperatures.
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  • 4
    Publication Date: 2013-09-10
    Description: We present a systematic study on the influence of pressure (0.1–600 MPa), temperature (750–1200 °C), carbon dioxide fugacity (log f CO 2  = –4.41 to 3.60) and time (2–12 hr) on the chemical and physical properties of carbonate rock. Our experiments aim to reproduce the conditions at the periphery of magma chamber where carbonate host rock is influenced by, but not readily assimilated by, magma. This permits the investigation of the natural conditions at which circulating fluids/gases promote infiltration reactions typical of metasomatic skarns that can involve large volumes of subvolcanic carbonate basements. Results show that, providing that carbon dioxide is retained in the pore space, decarbonation does not proceed at any magmatic pressure and temperature. However, when the carbon dioxide is free to escape, decarbonation can occur rapidly and is not hindered by a low initial porosity or permeability. Together with carbon dioxide and lime, portlandite, a mineral commonly found in voluminous metasomatic skarns, readily forms during carbonate decomposition. Post-experimental analyses highlight that thermal microcracking, a result of the highly anisotropic thermal expansion of calcite, exerts a greater influence on rock physical properties (porosity, ultrasonic wave velocities and elastic moduli) than decarbonation. Our data suggest that this will be especially true at the margins of dykes or magma bodies, where temperatures can reach up to 1200 °C. However, rock compressive strength is significantly reduced by both thermal cracking and decarbonation, explained by the relative weakness of lime + portlandite compared to calcite, and an increase in grain size with increasing temperature. Metasomatic skarns, whose petrogenetic reactions may involve a few tens of cubic kilometres, could therefore represent an important source of volcanic instability.
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 5
    Publication Date: 2016-01-22
    Description: The weakest explosive volcanic eruptions globally, Strombolian explosions and Hawaiian fountaining, are also the most common. Yet, despite over a hundred years of observations, no classifications have offered a convincing, quantitative way of demarcating these two styles. New observations show that the two styles are distinct in their eruptive time scale, with the duration of Hawaiian fountaining exceeding Strombolian explosions by ~300–10,000 s. This reflects the underlying process of whether shallow-exsolved gas remains trapped in the erupting magma or is decoupled from it. We propose here a classification scheme based on the duration of events (brief explosions versus prolonged fountains) with a cutoff at 300 s that separates transient Strombolian explosions from sustained Hawaiian fountains.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 6
    Publication Date: 2011-09-01
    Description: The recent Eyjafjallajokull (Iceland) eruption strikingly underlined the vulnerability of a globalized society to the atmospheric dispersal of volcanic clouds from even moderate-size eruptions. Ash aggregation controls volcanic clouds dispersal by prematurely removing fine particles from the cloud and depositing them more proximally. Physical parameters of ash aggregates have been modeled and derived from ash fallout deposits of past eruptions, yet aggregate sedimentation has eluded direct measurement, limiting our ability to predict the dispersal of volcanic clouds. Here we use field-based, high-speed video analysis together with laboratory experiments to provide the first in situ investigation and parameterization of the physical features and settling dynamics of ash aggregates from a volcanic cloud. In May 2010, high-speed video footage was obtained of both ash particles and aggregates settling from the Eyjafjallajokull volcano eruption cloud at a distance of 7 km from the vent; fallout samples were collected simultaneously. Experimental laboratory determinations of the density, morphology, and settling velocity of individual ash particles enable their distinction from aggregates. The combination of field and experimental analyses allows a full characterization of the size, settling velocity, drag coefficient, and density distributions of ash aggregates as well as the size distribution of their component particles. We conclude that ash aggregation resulted in a tenfold increase in mass sedimentation rate from the cloud, aggravating the ash hazard locally and modifying cloud dispersal regionally. This study provides a valuable tool for monitoring explosive eruptions, capable of providing robust input parameters for models of cloud dispersal and consequent hazard forecast.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 7
    Publication Date: 2016-12-02
    Description: We have refined the clinopyroxene-based hygrometer published by Armienti et al. (2013) for a better quantitative understanding of the role of H 2 O in the differentiation of Etnean magmas. The original calibration data set has been significantly improved by including several experimental clinopyroxene compositions that closely reproduce those found in natural Etnean products. To verify the accuracy of the model, some randomly selected experimental clinopyroxene compositions external to the calibration data set have been used as test data. Through a statistic algorithm based on the Mallows’ C P criterion, we also check that all model parameters do not cause data overfitting, or systematic error. The application of the refined hygrometer to the Mt. Etna 2011–2013 lava fountains indicates that most of the decreases in H 2 O content occur at P 〈 100 MPa, in agreement with melt inclusion data suggesting abundant H 2 O degassing at shallow crustal levels during magma ascent in the conduit and eruption to the surface.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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  • 8
    Publication Date: 2014-05-16
    Description: In this study, we have used electron-microprobe mapping to investigate plagioclase compositional evolution due to cooling kinetics. We re-analyzed five run-products from a prior study ( Iezzi et al. 2011 ), crystallized by cooling a natural andesitic melt from 1300 to 800 °C at 25, 12.5, 3, 0.5, and 0.125 °C/min under atmospheric pressure and air redox state. As the cooling rate decreases, the texture of large plagioclases changes from skeletal to hollow to nearly equant. In this study, we use X-ray map data to obtain a database of 12 275 quantitative chemical analyses. The frequency of An-rich plagioclases showing disequilibrium compositions substantially increases with increasing cooling rate. At 25 and 12.5 °C/min the distribution is single-mode and narrow, at 0.5 and 0.125 °C/min is single-mode but very broad, whereas at the intermediate cooling rate of 3 °C/min two distinct plagioclase populations are present. This intermediate cooling rate is fast enough to cause departure from equilibrium for the crystallization of the An-rich population but also sufficiently slow that An-poor plagioclases nucleate from the residual melt. We interpret our findings in the context of time-temperature-transformation (TTT) diagrams, and infer the crystallization kinetics of plagioclase in the experiments. Compositional trends and our inferences regarding TTT systematics are consistent with two discrete nucleation events that produced separate populations of plagioclase (i.e., An-rich and An-poor populations) at 3 °C/min. Using plagioclase-melt pairs as input data for the thermometric reaction between An and Ab components, we find that plagioclase mirrors very high- (near-liquidus) crystallization temperatures with increasing cooling rate. These results have important implications for the estimate of post-eruptive solidification conditions. Lava flows and intrusive bodies from centimeters to a few meters thick are characterized by a short solidification time and a significant thermal diffusion. Under such circumstances, it is possible to crystallize plagioclases with variable and disequilibrium chemical compositions simply by cooling a homogeneous andesitic melt. X-ray element maps enrich the study of plagioclase compositional variations generated under conditions of rapid cooling.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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  • 9
    Publication Date: 2017-06-02
    Description: The April to May 2010 eruption of Eyjafjallajökull (Iceland) volcano was characterized by a large compositional variability of erupted products. To contribute to the understanding of the plumbing system dynamics of this volcano, we present new EMPA and LA-ICP-MS data on groundmass glasses of ash particles and minerals erupted between April 15 and 22. The occurrence of disequilibrium textures in minerals, such as resorption and inverse zoning, indicate that open system processes were involved in determining the observed compositional variability. The variation of major and trace element data of glasses corroborates this hypothesis indicating that mixing between magma batches with different compositions interacted throughout the whole duration of the eruption. In particular, the arrival of new basaltic magma into the plumbing system of the volcano destabilized and remobilized magma batches of trachyandesite and rhyolite compositions that, according to geophysical data, might have intruded as sills over the past 20 years beneath the Eyjafjallajökull edifice. Two mixing processes are envisaged to explain the time variation of the compositions recorded by the erupted tephra. The first occurred between basaltic and trachyandesitic end-members. The second occurred between trachyandesite and rhyolites. Least-squares modeling of major elements supports this hypothesis. Furthermore, investigation of compositional histograms of trace elements allows us to estimate the initial proportions of melts that interacted to generate the compositional variability triggered by mixing of trachyandesites and rhyolites.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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  • 10
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