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  • 1
    Publication Date: 2015-05-26
    Description: This article presents electrocaloric effect in Ba 0.85 Ca 0.15 Ti 0.9 Zr 0.1 O 3 (BCTZO) using an indirect approach based on Maxwell's relations. The peak electrocaloric performance is found to be an adiabatic temperature change of 0.41 K with electrocaloric strength of 19 mK cm/kV and a heat carrying capacity of ~0.17 J/g under an electric field of 0–21.5 kV/cm. The ferroelectric hysteresis scaling relations for coercive field ( E C ), remnant polarization ( P r ), and hysteresis area (〈 A 〉) as a function of temperature ( T ) are also systematically investigated. The power-law temperature exponents are obtained for all the hysteresis parameters. The scaling relations are established as E c ∝ T −0.6584 , P r ∝ T −1.59 , and 〈 A 〉 ∝ T −1.01623 . The presented scaling relations are compared with those reported in the literature for other ferroelectric materials.
    Print ISSN: 1546-542X
    Electronic ISSN: 1744-7402
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Wiley
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  • 2
    Publication Date: 2014-12-21
    Description: Present study introduces a novel energy conversion cycle for giant electro-mechanical energy conversion using ferroelectric materials. The proposed cycle is used to perform indirect measurements for harnessable energy densities of two well-known configurations ((0.5PbZrO 3 -0.5Pb(Ni 1/3 Nb 2/3 )O 3 : (PZ-PNN) and 0.9Pb(Zr 1/2 Ti 1/2 )O 3 -0.1Pb(Zn 1/3 Nb 2/3 )O 3 : (0.9PZT-0.1PZN)). PZ-PNN is depicted to illustrate an energy density of 70 kJ/m 3 under the conditions of 0–106 MPa applied stress and 1–15 kV/cm electric field. On the other hand, a maximum energy density of 50 kJ/m 3 is obtained for 0.9PZT-0.1PZN under ambient conditions of 0–173 MPa compressive stress and 1 to 18 kV/cm electric field.
    Print ISSN: 1546-542X
    Electronic ISSN: 1744-7402
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Wiley
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  • 3
    Publication Date: 2016-02-17
    Description: Polyvinylidene di-fluoride-based polymers were investigated for elastocaloric and barocaloric effects. Bulk samples were subjected to uniaxial tensile and hydrostatic loading. Resulting strain profile (function of temperature) was used to predict the temperature change. A peak elastocaloric effect of 1.8 K was observed at 298 K (15 MPa). Alternately, a large barocaloric effect of ∼6 K was observed at 300 K (200 MPa). This was further improved to an astounding ∼19 K near 368 K (200 MPa). The results of this study are expected to greatly benefit the field of ferroelectric solid-state refrigeration and open another horizon for future exploration of multicaloric effects in ferroelectric polymers.
    Print ISSN: 0003-6951
    Electronic ISSN: 1077-3118
    Topics: Physics
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  • 4
    Publication Date: 2017-06-03
    Description: Ferroelectric materials are being actively explored for next-generation solid-state cooling technology. Even though bulk materials possess an advantage in terms of overall heat extraction capacity, their performance is limited due to low adiabatic temperature change. In this regard, the present article explores enhanced cooling capacity of bulk polycrystalline Pb 0.99 Nb 0.02 (Zr 0.95 Ti 0.05 ) 0.08 O 3 (PNZT) through external-field mediation and coupled caloric effects. Barocaloric (BC) and electrocaloric (EC) effects were indirectly estimated using polarization versus electric field (P-E) loops (under varying pressure and temperature). It was observed that under applied pressure of 325 MPa, ∆T EC could be improved from 1 K to 4.5 K. Similarly, a peak unbiased ∆T BC of 1.5 K could be enhanced to 5.3 K under an electric field of 5 MV.m −1 . These figures correspond to an improvement of ~400% over the unbiased values. The results are indicative of the potential of multicaloric cooling capacity of bulk ferroelectric materials. This article is protected by copyright. All rights reserved.
    Print ISSN: 0002-7820
    Electronic ISSN: 1551-2916
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Wiley
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