ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Cumulated Ylides, VII. A Method for the Synthesis of α,β-Unsaturated Carboxylic CompoundsPhosphacumulene ylides 1 add alcohols, thiols, and NH-acidic compounds to form phosphoranes 3, which react with aldehydes to give esters, thiol esters, imidates, thioimidates, amidines, azolides, and sulfonamides of α,β-unsaturated carboxylic acids.
Notes:
Phosphacumulen-Ylide 1 addieren Alkohole, Thiole und NH-acide Verbindungen zu Phosphoranen 3, die sich mit Aldehyden zu Estern, Thiolestern, Imidsäureestern, Imidsäurethioestern, Amidinen, Azoliden sowie Sulfonamiden α,β-ungesättigter Carbonsäuren umsetzen lassen.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19801130311
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