ISSN:
1588-2837
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Abstract Кинетику реакции замещения 4,4'-бипиридина (4,4'-bpy) цианидом в Fe(CN)5(4,4'-bpy)3− при 298 К исследовали в различных изодизлектричских бинарных водных смесях. Экспериментальные данные подчиняются уравнению: $$\delta \Delta G_{exp}^ \ne = a\delta A_m + b\delta B_m + cG^{exc} $$
Notes:
Abstract The kinetics of replacement of 4,4′-bipyridine, (4,4′bpy), by cyanide in [Fe(CN)5(4,4′bpy)]3− at 298 K have been studies in various isodielectric binary aqueous mixtures. The experimental data are well correlated through the following equation: $$\delta \Delta G_{exp}^ \ne = a\delta A_m + b\delta B_m + cG^{exc} $$ where Am, Bm ans Gexc are the acidity vector, the basicity vector and the excess Gibbs free energy of the mixture, respectively.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02070967
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