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Effect of silver salts on emulsion polymerization systems containing butadiene (1947)

Rainard, L. W.

Hoboken, NJ : Wiley-Blackwell

Journal of Polymer Science 2 (1947), S. 16-20

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ISSN: 0022-3832

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The addition of silver nitrate to polymerizable systems containing butadiene can result in increased over-all rates of conversion. When butadiene is the only monomer and a cationic soap is used the addition of silver nitrate causes* a significant decrease in rate. The most active system studied was one which contained butadiene, styrene, a cationic soap, a peroxide, and silver nitrate. Comparison runs in a GR-S type formulation with silver nitrate and potassium ferricyanide indicate that the silver salt is the more effective in producing higher over-all rates of conversion.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1947.120020104

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