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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 19 (1984), S. 3287-3300 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Structures within commercial calcined needle-cokes are characterized by optical microscopy to reveal optical texture and by scanning electron microscopy before and after etching with chromic acid solution at 400 to 423 K. The needle-cokes exhibit an optical texture of medium and coarse-grained mosaics, acicular flow domains and flow domains. The etching studies indicate that the acicular flow domains are made up of rolled and convoluted lamellae which etch to form laths (needle-like) ∼ 3 μm across. The mosaics appear when the rolled structures are viewed microscopically sectioned perpendicular to the lamellae. The acicular flow domains appear in longitudinal section. The etching of the flow domains shows that they have a sedimentary structure, 1 to 2 μm layer thickness, suggesting that mesophase coalesces within a layer but not between layers. A model is proposed to explain the origin and separation of structures in needle-cokes as created in the delayed coker.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 18 (1983), S. 3161-3176 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract This review summarizes current descriptions of the science and technology of graphite manufacture. The delayed coking process is outlined and mechanisms of coke formation put forward including considerations of the composition of feedstocks. As graphite manufacture uses calcined delayed cokes of which the most valuable is needle-coke, a comparison of rotary kiln, rotary hearth and vertical shaft calciners is made. Grinding and sizing of calcined coke is important as this with the binder pitch leads to baked carbon. The stages in the manufacturing process are described as mixing, forming, extrusion, moulding, baking, impregnation and graphitization. The more advanced processing technology includes isostatic hot pressing, artifact densifications, high pressure impregnation/baking and binderless graphitization. A comprehensive list of references is included.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 18 (1983), S. 3695-3704 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A green needle-coke was heated from 773 to 1323 K at 50 K intervals. The following properties were assessed: bulk dimensions, optical texture, fissure development, microstrength and elemental composition. It was observed that volumetric shrinkage of the green needle-coke commenced at about 900 K and appears to be largely complete at 1200 K. The shrinkage is 7%. The proportion of anisotropic components which make up the optical texture of needle-coke are unaffected by calcining. Contraction fissuring develops preferentially in domain optical texture, the shape of fissures being determined by lamellar orientation within the domain. Fissuring also appears to be complete at 1200 K. The microstrength of needle-coke increases continuously with calcining temperature.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 18 (1983), S. 3712-3720 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Failure mechanisms in baked carbons prepared from oxidized needle-coke and a coal-tar pitch binder are examined in terms of their optical texture and microstrength. Models are presented which describe interfaces between binder coke and filler coke and the failure mechanisms at these interfaces. Crack growth can occur at the interface between binder and filler; crack growth can interconnect the fissured interfaces between oxidized filler coke and binder; crack growth can occur between binder and filler cokes across a wetted/ keyed interface.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 18 (1983), S. 3705-3711 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract This study examines the microstrength, optical texture and bonding of baked carbons made from oxidized filler cokes and a pitch binder. Commercial needle-cokes and coke from a coal extract, after oxidation in the range of 0 to 20 wt% loss, were mixed with a coal-tar pitch and baked to produce a series of carbon artifacts. The microstrengths of these artifacts were measured and the interfaces between coke components were examined by optical microscopy. The microstrengths of carbon artifacts containing oxidized needle-coke filler decreases with increasing extent of oxidation of the filler. However, the strength of carbon artifacts containing oxidized coal extract coke filler increases with increasing extent of oxidation of the filler. Differences in wettability of the filler particles by the pitch appear to cause these changes in microstrength. The pitch appears to be unable to penetrate into the oxidation topography of the needle-coke surface at levels of oxidation below 20 wt% but can penetrate into the larger surface features of the oxidized coal extract filler coke. Penetration of the pitch into the oxidation topography of the filler cokes produces a wetted/keyed interface and improves the bonding between the filler and binder cokes in the resultant artifact.
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  • 6
    Publication Date: 2020-09-01
    Description: Context. Recent surveys of the Galactic plane in the dust continuum and CO emission lines reveal that large (≳50 pc) and massive (≳105 M⊙) filaments, know as giant molecular filaments (GMFs), may be linked to Galactic dynamics and trace the mid-plane of the gravitational potential in the Milky Way. Yet our physical understanding of GMFs is still poor. Aims. We investigate the dense gas properties of one GMF, with the ultimate goal of connecting these dense gas tracers with star formation processes in the GMF. Methods. We imaged one entire GMF located at l ~ 52–54° longitude, GMF54 (~68 pc long), in the empirical dense gas tracers using the HCN(1–0), HNC(1–0), and HCO+(1–0) lines, and their 13C isotopologue transitions, as well as the N2H+(1–0) line. We studied the dense gas distribution, the column density probability density functions (N-PDFs), and the line ratios within the GMF. Results. The dense gas molecular transitions follow the extended structure of the filament with area filling factors between 0.06 and 0.28 with respect to 13CO(1–0). We constructed the N-PDFs of H2 for each of the dense gas tracers based on their column densities and assumed uniform abundance. The N-PDFs of the dense gas tracers appear curved in log–log representation, and the HCO+ N-PDF has the flattest power-law slope index. Studying the N-PDFs for sub-regions of GMF54, we found an evolutionary trend in the N-PDFs that high-mass star-forming and photon-dominated regions have flatter power-law indices. The integrated intensity ratios of the molecular lines in GMF54 are comparable to those in nearby galaxies. In particular, the N2H+/13CO ratio, which traces the dense gas fraction, has similar values in GMF54 and all nearby galaxies except Ultraluminous Infrared Galaxies. Conclusions. As the largest coherent cold gaseous structure in our Milky Way, GMFs, are outstanding candidates for connecting studies of star formation on Galactic and extragalactic scales. By analyzing a complete map of the dense gas in a GMF we have found that: (1) the dense gas N-PDFs appear flatter in more evolved regions and steeper in younger regions, and (2) its integrated dense gas intensity ratios are similar to those of nearby galaxies.
    Print ISSN: 0004-6361
    Electronic ISSN: 1432-0746
    Topics: Physics
    Published by EDP Sciences
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  • 7
    Publication Date: 1983-11-01
    Print ISSN: 0022-2461
    Electronic ISSN: 1573-4803
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Springer
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  • 8
    Publication Date: 1984-10-01
    Print ISSN: 0022-2461
    Electronic ISSN: 1573-4803
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Springer
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  • 9
    Publication Date: 2016-06-04
    Description: Image cubes of differential column density as a function of dust temperature are constructed for Galactic Centre molecular cloud G0.253+0.016 (‘The Brick’) using the recently described PPMAP procedure. The input data consist of continuum images from the Herschel Space Telescope in the wavelength range 70–500 μm, supplemented by previously published interferometric data at 1.3 mm wavelength. While the bulk of the dust in the molecular cloud is consistent with being heated externally by the local interstellar radiation field, our image cube shows the presence, near one edge of the cloud, of a filamentary structure whose temperature profile suggests internal heating. The structure appears as a cool (~14 K) tadpole-like feature, ~6 pc in length, in which is embedded a thin spine of much hotter (~40–50 K) material. We interpret these findings in terms of a cool filament whose hot central region is undergoing gravitational collapse and fragmentation to form a line of protostars. If confirmed, this would represent the first evidence of widespread star formation having started within this cloud.
    Print ISSN: 1745-3925
    Electronic ISSN: 1745-3933
    Topics: Physics
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  • 10
    Publication Date: 2016-08-27
    Description: We present large-scale trends in the distribution of star-forming objects revealed by the Hi-GAL survey. As a simple metric probing the prevalence of star formation in Hi-GAL sources, we define the fraction of the total number of Hi-GAL sources with a 70 μm counterpart as the ‘star-forming fraction’ or SFF. The mean SFF in the inner galactic disc (3.1 kpc 〈 R GC 〈 8.6 kpc) is 25 per cent. Despite an apparent pile-up of source numbers at radii associated with spiral arms, the SFF shows no significant deviations at these radii, indicating that the arms do not affect the star-forming productivity of dense clumps either via physical triggering processes or through the statistical effects of larger source samples associated with the arms. Within this range of Galactocentric radii, we find that the SFF declines with R GC at a rate of –0.026 ±0.002 per kiloparsec, despite the dense gas mass fraction having been observed to be constant in the inner Galaxy. This suggests that the SFF may be weakly dependent on one or more large-scale physical properties of the Galaxy, such as metallicity, radiation field, pressure or shear, such that the dense sub-structures of molecular clouds acquire some internal properties inherited from their environment.
    Print ISSN: 0035-8711
    Electronic ISSN: 1365-2966
    Topics: Physics
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