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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    European journal of soil science 51 (2000), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Allophanic soils are known to accumulate organic matter, but the underlying mechanism is not well understood. Here we have investigated the sorption of humic acid (HA) by an allophanic clay in the presence of varied concentrations of either CaCl2 or NaCl as background electrolytes. Both the HA and the clay were separated from New Zealand soils. Much more HA was sorbed in CaCl2 than in NaCl of the same ionic strength. Apparently Ca2+ ions were more effective than Na+ ions in screening the negative charge on HA. In CaCl2 the HA molecule might also assume a more compact configuration than in NaCl. In the presence of CaCl2 sorption increased, reached a maximum, and then declined as the concentration of HA in solution was increased. This behaviour was not observed in NaCl where sorption showed a gradual and steady increase with HA concentration. We propose that ligand exchange occurs between the surface hydroxyl groups of allophane and the carboxylate groups of HA. As a result, the allophane–HA complex acquires negative charges, requiring the co-sorption of extraneous cations (Ca2+ or Na+) for charge balance. The Ca2+ co-sorbed can attract more HA to the complex possibly by a cation-bridging mechanism, giving rise to a maximum in sorption. The decline in sorption beyond the maximum may be ascribed to a decrease in the concentration of free Ca2+ ions through binding to HA molecules in solution. The increase in supernatant pH may be attributed to a ligand exchange reaction between the surface hydroxyls of allophane and the carboxylate groups of HA, and proton binding to the allophane–HA complex.
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    European journal of soil science 50 (1999), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The stabilization of organic matter in soil by interaction with aluminium (Al) or allophane is important in maintaining soil quality, and in retarding the decomposition of soil organic matter. Complexation of Al by soil organic matter may also ameliorate Al toxicity. Here we use 13C-NMR spectroscopy to assess the interaction of soil organic matter with both Al and allophane in two poorly drained podzols containing only trace amounts of iron. The 13C-NMR spectrum of the subsoil of the allophane-rich One Tree Point podzol shows an intense peak at 179 p.p.m., assigned to carbon in carboxylic acids. This peak shifts to 177 p.p.m. after removal of allophane (11% of the soil mass) by treatment with HF. We infer that the carboxyl groups in the organic matter are bonded to structural Al on the surface of allophane spherules. In the non-allophanic Te Kopuru podzol, on the other hand, the organic matter apparently interacts with Al ions in the soil solution. This soil also has more aromatic carbon and fewer carbons in carboxyl and carbohydrate structures than the allophanic sample. There is an indication that allophane stabilizes carbohydrate groups as well as carboxyl groups.
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 248 (1974), S. 220-221 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Here we establish that the surfaces of the crystalline hydroxides gibbsite (y-Al(OH)3) and goethite (a-FeOOH), both common soil components, are accessible to infrared study, and that their surface structures are well defined and closely related to their bulk structures. The observation of these ...
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  • 4
    ISSN: 1432-0789
    Keywords: Key words Forest floor ; Microbial phosphorus ; Microbial carbon ; C:P ratio ; Gross phosphorus mineralization and immobilization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Information on the mineralization of inorganic phosphate (Pi) from organically bound P (Po) during decomposition of forest floor and soil organic matter is vital for understanding P supply in forest ecosystems. Carbon (C) and phosphorus (P) fluxes were determined for forest floor samples from three Pinus radiata plots which had received no P (Control), 62.5 kg P ha–1 (Low P) and 125 kg P ha–1 (High P) 20 years before sampling. The P concentration of the forest floor samples had increased with fertilizer application, and the C:P ratio ranged between 585 and 1465. During a 9-week laboratory incubation 8.2–19.0% of the forest floor C was evolved as CO2-C. The amount of CO2 evolved from the forest floor of the Control plot was more than twice the amounts from the Low P and High P plots. There was little change in net P mineralization in the Control and Low P treatments throughout the incubation, but it increased slightly for the High P samples, suggesting a critical forest floor C:P ratio of 550 for net P mineralization. Changes in the 32P-specific activities of the Pi and microbial P pools during incubation, and concurrent changes in microbial-32P and 32Pi, indicated internal P cycling between these pools. The rate of internal P cycling varied with forest floor quality, and was highest in the High P forest floor. The High P samples had microbial C:P ratios of 22 : 1 which remained constant during the incubation, suggesting the microorganisms had adequate P levels.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of environmental contamination and toxicology 55 (1995), S. 162-169 
    ISSN: 1432-0800
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 53 (1979), S. 55-65 
    ISSN: 1573-5036
    Keywords: Aluminium hydrous oxides ; Goethite ; Iron hydrous oxides ; Mycorrhiza ; Phosphate ; Root exudates ; Ryegrass
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Pot trials using phosphated-goethite (bridging complex) as the source of P for ryegrass were established. No P was readily available to ryegrass until the surface was 〉40% covered with phosphate ions. Availability increased as the P level in solution increased up to 2 μM. Maximum availability was attained when the initial concentration of P in solution was 2 μM which occurred at about 75% coverage on geothite. Mycorrhiza increased the availability of phosphate at a level of about 0.5–2 μM P (60–70% coverage of the goethite surface). Laboratory experiments showed that citrate ions were particularly effective in displacing P from goethite and the Olsen reagent was a good predictor of P availability to ryegrass.
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  • 7
    ISSN: 1573-5036
    Keywords: nitrogen ; pasture ; phosphorus ; plant ; P fertility status ; season ; soil ; temporal variations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Temporal variations in plant production, plant P and some soil P (and N) pools were followed over 21 months in two New Zealand pasture soils of widely different P fertility status. Plant growth rates, and herbage composition at the high-fertility site, were closely linked to soil water use, with growth rates falling when soil water deficits exceeded 60 mm. Herbage P concentrations reflected P fertility, and varied with season, being generally higher in winter and lower in summer. A similar temporal pattern was also observed for labile organic P (NaHCO3-extractable P0) in both soils. In the low-fertility soil in spring, net mineralization was especially strong, but from early winter net immobilization occurred. Surprisingly, Olsen P also changed temporally in the high-fertility soil. The microbial biomass remained fairly constant throughout the year, whereas the P content of the biomass varied seasonally. Although microbial biomass was not a useful index of soil fertility, highest microbial P0 contents coincided with periods of maximum labile P0 mineralization, when herbage production was also at a peak. Net N-mineralization in the low-fertility soil, in contrast to the high-fertility soil, was low but varied seasonally, under standardised incubation conditions. Soil P and N dynamics were apparently synchronised in the low-fertility soil through soil microbial processes, with mineral N being negatively correlated with microbial P0 in samples collected two months later. The results of this investigation suggest that the demands of rapid and sustained pasture growth in spring and early summer can best be met by maximising the build-up of organic matter during the preceding autumn and winter. This practice could help to alleviate the common problem of feed shortage in North Island hill country pastures in late winter-early spring.
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  • 8
    Publication Date: 2006-05-01
    Description: Ground-based harvest operations in planted forests can adversely affect the soil and subsequently the productivity of the plantation. This study examined the effects of compaction, site preparation, and fertilization on soil physical and chemical properties and tree growth in a trial established at a second-rotation harvest on an imperfectly drained clay loam located in the North Island, New Zealand. Treatments were installed following harvest of Pinus radiata D. Don. There were four physical treatments: no treatment, compaction in rows by skidder, site preparation (rip and disk), and compaction followed by site preparation; the three nutrient treatments included no fertilizer, nitrogen (N), and N plus phosphorus (P). Response of P. radiata was studied for the first 4 years of growth. Compaction reduced survival of P. radiata at planting and during the first year of growth as the result of an increased oxygen deficit, caused by a reduction in macropore volume, and a shallower depth to the perched water table. Site preparation improved both survival of the seedlings and growth over 4 years. There was an initial growth response to N, but fertilizer did not increase survival of the seedlings. After 4 years, both site preparation and N plus P treatments gave approximately 10% extra growth, suggesting that N plus P may have been as effective as site preparation for improved growth of the trees that survived the first 2 years. However, since survival of seedlings is important to the economics of plantations, especially where planting densities are low, site preparation of soils with low macropore volume should be considered as a management tool.
    Print ISSN: 0045-5067
    Electronic ISSN: 1208-6037
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
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  • 9
    Publication Date: 1972-07-01
    Print ISSN: 0361-5995
    Electronic ISSN: 1435-0661
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by Wiley
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  • 10
    Publication Date: 1970-11-01
    Print ISSN: 0361-5995
    Electronic ISSN: 1435-0661
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by Wiley
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