ALBERT

Description: Produced by the incomplete combustion of fossil fuel and biomass, black carbon (BC) contributes to Arctic warming by reducing snow albedo and thus triggering a snow-albedo feedback leading to increased snowmelt. Therefore, it is of high importance to assess past BC emissions to better understand and constrain their role. However, only a few long-term BC records are available from the Arctic, mainly originating from Greenland ice cores. Here, we present the first long-term and high-resolution refractory black carbon (rBC) record from Svalbard, derived from the analysis of two ice cores drilled at the Lomonosovfonna ice field in 2009 (LF-09) and 2011 (LF-11) and covering 800 years of atmospheric emissions. Our results show that rBC concentrations strongly increased from 1860 on due to anthropogenic emissions and reached two maxima, at the end of the 19th century and in the middle of the 20th century. No increase in rBC concentrations during the last decades was observed, which is corroborated by atmospheric measurements elsewhere in the Arctic but contradicts a previous study from another ice core from Svalbard. While melting may affect BC concentrations during periods of high temperatures, rBC concentrations remain well preserved prior to the 20th century due to lower temperatures inducing little melt. Therefore, the preindustrial rBC record (before 1800), along with ammonium (NH4+), formate (HCOO−) and specific organic markers (vanillic acid, VA, and p-hydroxybenzoic acid, p-HBA), was used as a proxy for biomass burning. Despite numerous single events, no long-term trend was observed over the time period 1222–1800 for rBC and NH4+. In contrast, formate, VA, and p-HBA experience multi-decadal peaks reflecting periods of enhanced biomass burning. Most of the background variations and single peak events are corroborated by other ice core records from Greenland and Siberia. We suggest that the paleofire record from the LF ice core primarily reflects biomass burning episodes from northern Eurasia, induced by decadal-scale climatic variations.

Description: Produced by the incomplete combustion of fossil fuel and biomass, black carbon (BC) contributes to Arctic warming by reducing snow albedo and thus triggering a snow-albedo feedback leading to increased snow melting. Therefore, it is of high importance to assess past BC emissions to better understand and constrain their role. However, only few long-term BC records are available from the Arctic, mainly originating from Greenland ice cores. Here, we present the first long-term and high-resolution refractory black carbon (rBC) record from Svalbard, derived from the analysis of two ice cores drilled at the Lomonosovfonna ice field in 2009 (LF-09) and 2011 (LF-11) and covering 800 years of atmospheric emissions. Our results show that rBC concentrations strongly increased from 1860 on due to anthropogenic emissions and reached two maxima, at the end of the 19th century and in the middle of the 20th century. No increase in rBC concentrations during the last decades was observed, which is corroborated by atmospheric measurements elsewhere in the Arctic but contradicts a previous study from another ice core from Svalbard. While melting may affect BC concentrations during periods of high temperatures, rBC concentrations remain well-preserved prior to the 20th century due to lower temperatures inducing little melt. Therefore, the preindustrial rBC record (before 1800), along with ammonium (NH4+), formate (HCOO−) and specific organic markers (vanillic acid (VA) and p-hydroxybenzoic acid (p-HBA)), was used as a proxy for biomass burning. Despite numerous single events, no long-term trend was observed over the time period 1222–1800 for rBC and NH4+. In contrast, formate, VA and p-HBA experience multi-decadal peaks reflecting periods of enhanced biomass burning. Most of the background variations and single peak events are corroborated by other ice-core records from Greenland and Siberia. We suggest that the paleofire record from the LF ice core primarily reflects biomass burning episodes from Northern Eurasia, induced by decadal-scale climatic variations.

Description: The Amazon Basin is one of the major contributors to global biomass burning emissions. However, regional paleofire trends remain partially unknown. Due to their proximity to the Amazon Basin, Andean ice cores are suitable to reconstruct paleofire trends in South America and improve our understanding of the complex linkages between fires, climate and humans. Here we present the first refractory black carbon (rBC) ice-core record from the Andes as a proxy for biomass burning emissions in the Amazon Basin, derived from an ice core drilled at 6300 m a.s.l. from Illimani glacier in the Bolivian Andes and spanning the entire Holocene back to the last deglaciation 13 000 years ago. The Illimani rBC record displays a strong seasonality with low values during the wet season and high values during the dry season due to the combination of enhanced biomass burning emissions in the Amazon Basin and less precipitation at the Illimani site. Significant positive (negative) correlations were found with reanalyzed temperature (precipitation) data, respectively, for regions in Eastern Bolivia and Western Brazil characterized by a substantial fire activity. rBC long-term trends indirectly reflect regional climatic variations through changing biomass burning emissions as they show higher (lower) concentrations during warm/dry (cold/wet) periods, respectively, in line with climate variations such as the Younger Dryas, the 8.2 ka event, the Holocene Climatic Optimum, the Medieval Warm Period or the Little Ice Age. The highest rBC concentrations of the entire record occurred during the Holocene Climatic Optimum between 7000 and 3000 BC, suggesting that this outstanding warm and dry period caused an exceptional biomass burning activity, unprecedented in the context of the past 13 000 years. Recent rBC levels, rising since 1730 AD in the context of increasing temperatures and deforestation, are similar to those of the Medieval Warm Period. No decrease was observed in the 20th century, in contradiction with the global picture (broken fire hockey stick hypothesis).

Description: The Amazon Basin is one of the major contributors to global biomass burning emissions. However, regional paleofire trends remain particularly unknown. Due to their proximity to the Amazon Basin, Andean ice cores are suitable to reconstruct paleofire trends in South America and improve our understanding of the complex linkages between fires, climate and humans. Here we present the first refractory black carbon (rBC) ice-core record from the Andes as a proxy for biomass burning emissions in the Amazon Basin, derived from an ice core drilled at 6300 m a.s.l. from the Illimani glacier in the Bolivian Andes and spanning the entire Holocene back to the last deglaciation 13 000 years ago. The Illimani rBC record displays a strong seasonality with low values during the wet season and high values during the dry season due to the combination of enhanced biomass burning emissions in the Amazon Basin and less precipitation at the Illimani site. Significant positive (negative) correlations were found with reanalyzed temperature (precipitation) data for regions in eastern Bolivia and western Brazil characterized by substantial fire activity. rBC long-term trends indirectly reflect regional climatic variations through changing biomass burning emissions as they show higher (lower) concentrations during warm–dry (cold–wet) periods, in line with climate variations such as the Younger Dryas, the 8.2 ka event, the Holocene Climatic Optimum, the Medieval Warm Period and the Little Ice Age. The highest rBC concentrations of the entire record occurred during the Holocene Climatic Optimum between 7000 and 3000 BCE, suggesting that this exceptionally warm and dry period caused high levels of biomass burning activity, unprecedented in the context of the past 13 000 years. Recent rBC levels, rising since 1730 CE in the context of increasing temperatures and deforestation, are similar to those of the Medieval Warm Period. No decrease in fire activity was observed in the 20th century, in contradiction to global biomass burning reconstructions based on charcoal data.

Description: Light absorbing aerosols in the atmosphere and cryosphere play an important role in the climate system. Their presence in ambient air and snow changes the radiative properties of these systems, thus contributing to increased atmospheric warming and snowmelt. High spatio-temporal variability of aerosol concentrations and a shortage of long-term observations contribute to large uncertainties in properly assigning the climate effects of aerosols through time. Starting around AD 1860, many glaciers in the European Alps began to retreat from their maximum mid-19th century terminus positions, thereby visualizing the end of the Little Ice Age in Europe. Radiative forcing by increasing deposition of industrial black carbon to snow has been suggested as the main driver of the abrupt glacier retreats in the Alps. The basis for this hypothesis was model simulations using elemental carbon concentrations at low temporal resolution from two ice cores in the Alps. Here we present sub-annually resolved concentration records of refractory black carbon (rBC; using soot photometry) as well as distinctive tracers for mineral dust, biomass burning and industrial pollution from the Colle Gnifetti ice core in the Alps from AD 1741 to 2015. These records allow precise assessment of a potential relation between the timing of observed acceleration of glacier melt in the mid-19th century with an increase of rBC deposition on the glacier caused by the industrialization of Western Europe. Our study reveals that in AD 1875, the time when rBC ice-core concentrations started to significantly increase, the majority of Alpine glaciers had already experienced more than 80 % of their total 19th century length reduction, casting doubt on a leading role for soot in terminating of the Little Ice Age. Attribution of glacial retreat requires expansion of the spatial network and sampling density of high alpine ice cores to balance potential biasing effects arising from transport, deposition, and snow conservation in individual ice-core records.

Description: Light absorbing aerosols in the atmosphere and cryosphere play an important role in the climate system. Their presence in ambient air and snow changes radiative properties of these media, thus contributing to increased atmospheric warming and snowmelt. High spatio-temporal variability of aerosol concentrations and a shortage of long-term observations contribute to large uncertainties in properly assigning the climate effects of aerosols through time. Starting around 1860 AD, many glaciers in the European Alps began to retreat from their maximum mid-19th century terminus positions, thereby visualizing the end of the Little Ice Age in Europe. Radiative forcing by increasing deposition of industrial black carbon to snow has been suggested as the main driver of the abrupt glacier retreats in the Alps. Basis for this hypothesis were model simulations using elemental carbon concentrations at low temporal resolution from two ice cores in the Alps. Here we present sub-annually resolved, well-replicated concentration records of refractory black carbon (rBC; using soot photometry) as well as distinctive tracers for mineral dust, biomass burning and industrial pollution from the Colle Gnifetti ice core in the Alps from 1741–2015 AD. These records allow precise assessment of a potential relation between the timing of observed acceleration of glacier melt in the mid-19th century with an increase of rBC deposition on the glacier caused by the industrialization of Western Europe. Our study reveals that in 1875 AD, the time when European rBC emission rates started to significantly increase, the majority of Alpine glaciers had already experienced more than 80 % of their total 19th century length reduction. Industrial BC emissions can, therefore, not been considered as the primary forcing for the rapid deglaciation at the end of the Little Ice Age in the Alps. BC records from the Alps and Greenland also reveal the limitations of bottom-up emission inventories to represent a realistic evolution of anthropogenic BC emissions since preindustrial times.

Description: Recent large wildfires, such as those in Portugal in 2017, have devastating impacts on societies, economy, ecosystems and environments. However, wildfires are a natural phenomenon, which has been exacerbated by land use during the past millennia. Ice cores are one of the archives preserving information on fire occurrences over these timescales. A difficulty is that emission sensitivity of ice cores is often unknown, which constitutes a source of uncertainty in the interpretation of such archives. Information from specific and well-documented case studies is therefore useful to better understand the spatial representation of ice-core burning records. The wildfires near Pedrógão Grande in central Portugal in 2017 provided a test bed to link a fire event to its footprint left in a high-alpine snowpack considered a surrogate for high-alpine ice-core sites. Here, we (1) analysed black carbon (BC) and microscopic charcoal particles deposited in the snowpack close to the high-alpine research station Jungfraujoch in the Swiss Alps; (2) calculated backward trajectories based on ERA-Interim reanalysis data and simulated the transport of these carbonaceous particles using a global aerosol-climate model; and (3) analysed the fire spread, its spatial and temporal extent, and its intensity with remote-sensing (e.g. MODIS) Active Fire and Burned Area products. According to modelled emissions of the FINN v1.6 database, the fire emitted a total amount of 203.5 t BC from a total burned area of 501 km2 as observed on the basis of satellite fire products. Backward trajectories unambiguously linked a peak of atmospheric-equivalent BC observed at the Jungfraujoch research station on 22 June – with elevated levels until 25 June – with the highly intensive fires in Portugal. The atmospheric signal is in correspondence with an outstanding peak in microscopic charcoal observed in the snow layer, depositing nearly as many charcoal particles as during an average year in other ice archives. In contrast to charcoal, the amount of atmospheric BC deposited during the fire episode was minor due to a lack of precipitation. Simulations with a global aerosol-climate model suggest that the observed microscopic charcoal particles originated from the fires in Portugal and that their contribution to the BC signal in snow was negligible. Our study revealed that microscopic charcoal can be transported over long distances (1500 km) and that snow and ice archives are much more sensitive to distant events than sedimentary archives, for which the signal is dominated by local fires. The findings are important for future ice-core studies as they document that, for BC as a fire tracer, the signal preservation depends on precipitation. Single events, like this example, might not be preserved due to unfavourable meteorological conditions.