ISSN:
1572-9028
Keywords:
ammoximation in liquid phase with hydrogen peroxide
;
titanium silicalite
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract In the new EniChem process cyclohexanone oxime is directly synthesized by ammoximation of cyclohexanone with ammonia and hydrogen peroxide on titanium silicalite catalyst. The ammoximation reaction is suitable for the synthesis of several oximes by reaction of the corresponding ketones with ammonia and hydrogen peroxide on titanium silicalite. New results on ketones ammoximation and on reaction byproducts are reported. The effect of some reaction parameters on the oxime yield and on byproducts formation is discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02113858
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