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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © The Oceanography Society, 2015. This article is posted here by permission of The Oceanography Society for personal use, not for redistribution. The definitive version was published in Oceanography 28, no. 2 (2015): 182-197, doi:10.5670/oceanog.2015.41.
    Description: New England coastal and adjacent Nova Scotia shelf waters have a reduced buffering capacity because of significant freshwater input, making the region’s waters potentially more vulnerable to coastal acidification. Nutrient loading and heavy precipitation events further acidify the region’s poorly buffered coastal waters. Despite the apparent vulnerability of these waters, and fisheries’ and mariculture’s significant dependence on calcifying species, the community lacks the ability to confidently predict how the region’s ecosystems will respond to continued ocean and coastal acidification. Here, we discuss ocean and coastal acidification processes specific to New England coastal and Nova Scotia shelf waters and review current understanding of the biological consequences most relevant to the region. We also identify key research and monitoring needs to be addressed and highlight existing capacities that should be leveraged to advance a regional understanding of ocean and coastal acidification.
    Description: This project was supported in part by an appointment to the Internship/Research Participation Program at the Office of Water, US Environmental Protection Agency (EPA), administered by the Oak Ridge Institute for Science and Education through an interagency agreement between the US Department of Energy and the EPA. JS acknowledges support from NASA grant from NNX14AL84G NASA-CCS.
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/vnd.ms-excel
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-27
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Siedlecki, S. A., Salisbury, J., Gledhill, D. K., Bastidas, C., Meseck, S., McGarry, K., Hunt, C. W., Alexander, M., Lavoie, D., Wang, Z. A., Scott, J., Brady, D. C., Mlsna, I., Azetsu-Scott, K., Liberti, C. M., Melrose, D. C., White, M. M., Pershing, A., Vandemark, D., Townsend, D. W., Chen, C,. Mook, W., Morrison, R. Projecting ocean acidification impacts for the Gulf of Maine to 2050: new tools and expectations. Elementa: Science of the Anthropocene, 9(1), (2021): 00062, https://doi.org/10.1525/elementa.2020.00062.
    Description: Ocean acidification (OA) is increasing predictably in the global ocean as rising levels of atmospheric carbon dioxide lead to higher oceanic concentrations of inorganic carbon. The Gulf of Maine (GOM) is a seasonally varying region of confluence for many processes that further affect the carbonate system including freshwater influences and high productivity, particularly near the coast where local processes impart a strong influence. Two main regions within the GOM currently experience carbonate conditions that are suboptimal for many organisms—the nearshore and subsurface deep shelf. OA trends over the past 15 years have been masked in the GOM by recent warming and changes to the regional circulation that locally supply more Gulf Stream waters. The region is home to many commercially important shellfish that are vulnerable to OA conditions, as well as to the human populations whose dependence on shellfish species in the fishery has continued to increase over the past decade. Through a review of the sensitivity of the regional marine ecosystem inhabitants, we identified a critical threshold of 1.5 for the aragonite saturation state (Ωa). A combination of regional high-resolution simulations that include coastal processes were used to project OA conditions for the GOM into 2050. By 2050, the Ωa declines everywhere in the GOM with most pronounced impacts near the coast, in subsurface waters, and associated with freshening. Under the RCP 8.5 projected climate scenario, the entire GOM will experience conditions below the critical Ωa threshold of 1.5 for most of the year by 2050. Despite these declines, the projected warming in the GOM imparts a partial compensatory effect to Ωa by elevating saturation states considerably above what would result from acidification alone and preserving some important fisheries locations, including much of Georges Bank, above the critical threshold.
    Description: This research was financially supported by the Major Special Projects of the Ministry of Science and Technology of China (2016YFC020600), the Young Scholars Science Foundation of Lanzhou Jiaotong University (2018033), and the Talent Innovation and Entrepreneurship Projects of Lanzhou (2018-RC-84).
    Keywords: PM2.5 ; Contamination characteristics ; Meteorological factors ; Metal source analysis ; Lanzhou
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 66 (1962), S. 557-559 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 27 (1955), S. 1306-1307 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 62 (1958), S. 372-373 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 61 (1957), S. 1314-1318 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 1372-1385 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The heat capacity of CH3D on graphite has been measured at low temperatures (0.3–7 K) and shown to have a Schottky anomaly resulting from the difference in energy between states with the single deuterium atom pointing away from the surface (D up) and states where the deuterium atom is part of the tripod of atoms pointing towards the surface (D down). The energy difference is 380±20 μeV with the D-down configuration being the more stable. Incoherent neutron scattering spectra of CH3D adsorbed on exfoliated graphite have been used to resolve the finer detail of the tunneling splittings in the system. The energy levels can be described quantitatively in terms of five parameters, the splitting between D-up and D-down configurations and two pairs of parameters, one pair related to the rotational potential about the unique C–H(D) bond normal to the surface and the other pair to rotation about one of the three equivalent C–H(D) bonds pointing towards the surface. Comparison of the results from CH3D and earlier results from CH4 show that both potentials contain two Fourier components, approximately 75% of a threefold and 25% of a sixfold component in phase with one another. The values originally obtained from the CH4 tunneling spectrum for the two barrier heights 202 and 172 cm−1 for rotation about the unique and nonunique axes, respectively, are shown to have an uncertainty of about 5% resulting from the approximations used for the shape of the potential in the interpretation of the earlier experiment.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Quartz–sillimanite segregations, quartz–albite lithologies (Ab95–98), and Kiruna-type low-Ti iron-oxide deposits are associated with late- to post-tectonic (c. 1055 Ma) leucogranites of Lyon Mountain Gneiss (LMG) in the Adirondack Mountains, New York State. Most recent interpretations of these controversial features, which are global in occurrence, favour hydrothermal origins in agreement with results presented here.Field relations document that quartz–sillimanite veins and nodules cut, and therefore post-date, emplacement of host LMG leucogranites. Veins occur in oriented fracture networks, and aligned trains of nodules are interpreted as disrupted early veins. Late dykes of leucogranite cut veins and nodules demonstrating formation prior to terminal magmatism. Veins and nodules consist of sillimanite surrounded by quartz that commonly embays wall-rock feldspar indicating leaching of Na and K from LMG feldspar by acidic hydrothermal fluids. Subsequent, and repeated, ductile flow disrupted earlier veins into nodular fragments but produced little grain shape fabric.Geochemical and petrographic studies of quartz–albite rock indicate that it formed through metasomatic replacement (albitization) of LMG microperthite by sodic hydrothermal fluids that resulted in diagnostic checkerboard albite. Low-Ti iron-oxide ores are commonly associated with the quartz–albite sub-unit, and it is proposed that hydrothermal fluids related to albitization transported Fe as well. The regional extent of sodic alteration suggests large quantities of surface-derived hydrothermal fluids. Fluid inclusion and oxygen isotope data are consistent with high temperature, regionally extensive fluids consisting primarily of evolved surface-derived brines enriched in Na and Cl. Quartz–sillimanite veins and nodules, which are significantly more localised phenomena and require acidic fluids, were most likely formed from local magmatic fluids in the crystallizing carapaces of LMG plutons.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 11 (1993), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract ‘Peak’metamorphic carbon isotope fractionations between calcite and graphite (ΔCal–Gr) in marbles and calc-silicates from the Cucamonga granulite terrane (San Gabriel Mountains, California) range from 3.48 to 2.90%. The data are used to test three previously published calibrations of the calcite–graphite carbon isotope thermometer. An empirical calibration of the calcite–graphite carbon isotope thermometer gives temperatures of 700–750°C; a theoretical–experimental calibration of the system gives temperatures of 760°–870°C; an experimental calibration gives temperatures of 870–1300°C. Temperatures calculated using the empirical calibration are in agreement with those calculated from garnet-based cation exchange thermometry when uncertainty is considered. Temperatures calculated using the theoretical–experimental calibration overlap the upper range of cation exchange thermometry temperatures and range to 50°C higher. The experimental calibration yields temperatures from 50 to 480°C higher than those from cation exchange thermometry. Moreover, temperatures from the experimental calibration are also inconsistent with mineral and melt equilibria in the granulite phase assemblage.Despite the better agreement between cation exchange thermometry and the empirical calibration of the calcite–graphite system, temperatures calculated using the theoretical–experimental calibration may be real peak metamorphic temperatures. If retrograde diffusion partially reset garnet-based cation exchange thermometers by c. 50°C, then the cation exchange temperatures are consistent with those from the theoretical–empirical calibration. Thermometric evidence from biotite dehydration melting equilibria is consistent with either the empirical calibration if melting was fluid-present, or the theoretical–experimental calibration if melting was fluid-absent.
    Type of Medium: Electronic Resource
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