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  • 1
    Electronic Resource
    Electronic Resource
    Chemoselective acylation for the synthesis of model compounds of polynucleotide analogs (1986)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 24 (1986), S. 243-248 
    Details
    ISSN: 0887-6258
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1986.140240601
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  • 2
    Electronic Resource
    Electronic Resource
    Synthesis and polymerization of γ-alkoxy-β-hydroxypropyl acrylates (1980)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 3403-3411 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Several γ-alkoxy-β-hydroxypropyl acrylates were synthesized and polymerized. Both poly(MHPA) (IVd) and poly(MHPMA) (IVa) hydrogels possess high values of equilibrium water content, about seven and three times, respectively, that of the poly(β-hydroxyethyl methacrylate) hydrogel. These rather high values are attributed tentatively to the presence of a hydrophilic γ-methoxy-β-hydroxypropyl side group on the acrylic backbone.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1980.170181207
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  • 3
    Electronic Resource
    Electronic Resource
    Studies of some bioactive N-p-methacrylamidobenzoic esters (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 19 (1981), S. 3333-3343 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Preparations of four typical bioactive esters of N-p-methacrylamidobenzoic monomers and their reactive polymers as immobilized trypsin carriers are described. N-p-methacrylamidobenzoic active ester monomers containing —COONB, —COOSu, —COOObt, or —COOBT group can react with an aliphatic amine such as benzylamine at room temperature to give an identical product, N-benzyl-p-methacrylamidobenzamide. However, only monomers with —COOObt or —COOBT group can also react with an aromatic amine such as aniline to give N-phenyl-p-methacrylamidobenzamide. These monmoers polymerized readily in solution with azobisisobutyronitrile as free-radical initiator; the polymers were used to immobilize trypsin. Among the four different active esters for the immobilization of trypsin, thE HONB and HOSu active ester showed rather higher bioactivities than the HOObt or HOBT active ester under the same conditions. Both P(MABONB)-trypsin and P(MABOSu)-trypsin matrices possess higher biological activities by about four or three times that of P(MABOObt)-trypsin or P(MABOBT)-trypsin matrices, respectively. It is proposed that these rather high bioactivities may be attributed to the “specific” aminolysis of reactive polymer with —COONB or —COOSu active ester group by aliphatic amino substituents.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.170191226
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  • 4
    Electronic Resource
    Electronic Resource
    Synthesis and polymerization of optically active L-[α-(N-p-acryloxybenzoyl)alanine ethyl esters] (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2413-2425 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New optically active monomers L-[α-(N-p-acryloxybenzoyl)alanine ethyl esters] (I) and their polymers were synthesized. The title monomers (I) were prepared by the reaction of 1-p-acryloxybenzoyloxy-4-chlorobenzotriazoles (II) with L-alanine ethyl ester hydrochloride, by aminolysis of the active monoester. The new typical active ester (II) was synthesized by the N-hydroxy compound active-ester methods in excellent yield. Before the synthesis of the optically active monomers was carried out, a model study of the aminolysis of the two active esters was performed.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1984.170221011
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  • 5
    Electronic Resource
    Electronic Resource
    Synthesis of poly(vinyl alcohol) containing asymmetric nucleic acid base derivatives as grafted pendants (1985)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 23 (1985), S. 1321-1332 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The preparations of new model polymers of polynucleotides with linear poly(vinyl alcohol) (PVA) backbones and an optically active nucleic acid base derivative as a pending side chain are described. (±)-, (+)-, and (-)-2-(thymin-1-yl)propionic acid were grafted onto PVA through ester bonds by direct coupling with dicyclohexylcarbodiimide (DCC) in the presence of highly active catalyst 4-pyrrolidinopyridine (PPY) to give optically active graft polymers. The corresponding monomer and dimer models have been prepared.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1985.170230506
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  • 6
    Electronic Resource
    Electronic Resource
    Synthesis of polyamides from active O,O′-diacyl derivatives of N-hydroxy compounds and diamines under mild conditions (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 19 (1981), S. 2091-2101 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two new routes to polyamides were established, based on the polycondensation of two new typical active diesters: the active diester of N-hydroxy-5-norbornene-2,3-dicarboximide, such as N,N′-(terephthaloyldioxy)bis(5-norbornene-2,3-dicarboximide), and the active diester of 3-hydroxy-4-oxo-3,4-dihydro-1,2,3-benzotriazine, such as 3,3′-(isophthaloyldioxy)bis(4-oxo-3,4-dihydro-1,2,3-benzotriazine) with diamines. The polycondensation occurred at room temperature in solution without added catalyst. Dipolar aprotic solvents which included dimethyl sulfoxide and N-methyl-2-pyrrolidone were used as solvents for polymerization. Before polymer synthesis the aminolysis of two active monoesters was carried out as a model compound study.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.170190820
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  • 7
    Electronic Resource
    Electronic Resource
    Studies of some bioactive N-p-methacrylamidobenzoic esters (1982)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 20 (1982), S. 1151-1151 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1982.170200424
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