Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
89 (1988), S. 6771-6776
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The technique of infrared multiphoton ionization was used to obtain state specific internal conversion rates in CrO2 Cl2. Using tunable 10 ps dye laser pulses, different vibrational states in the B1 manifold were excited and the energy relaxation was monitored by an IR ps laser pulse. The relaxation can be characterized by a fast component, which is due to internal conversion to the 1 A1 state, and a slow component, which is due to cooling of the vibrationally hot 1 A1 ground state. The nonradiative energy transfer rate changes by almost three orders of magnitude for an excess vibrational energy change of merely 550 cm−1. The possibility of state specific pumping of 1 A1 is also pointed out.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.455351
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