ISSN:
0009-2940
Keywords:
o-Quinoid hetarenes / Isoindoles, cycloaddition reactions with / Dienophiles, CC
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Studies on the Chemistry of Isoindoles and Isoindolenines, XXXVI - Reactions of 2-Alkyl-2H-isoindoles with Maleic Imides2-Alkyl-2H-isoindoles 2 react with maleic imides 4 exclusively in position 1 and 3 by cycloaddition to form Diels-Alder adducts. The transformation of the endo isomers 6 into the thermodynamically more stable exo isomers 7 depends on the dienophile. The cycloaddition is useful for analytical detection of o-quinoid hetarenes 2 and for the synthesis of 7-azabicyclo[2.2.1]heptenes.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901230225
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