ISSN:
0009-2940
Keywords:
Hexaphenyltantalate
;
Hexatolytantalate
;
Trigonal prismatic coordination
;
Transition metals
;
Structure elucidation
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
By reacting TaCl5 with LiC6H5 and LiC6H4-4-CH3 salts, the anions Ta(C6H5)6 and Ta(C6H4-4-CH3)6 were obtained in small yields. They were structurally characterized by low-temperature single-crystal structure determination and found to have quite similar structures, which can be described as slightly distorted trigonal prismatic.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971300715
Permalink