ISSN:
1573-5001
Keywords:
heteronuclear NMR
;
heteronuclear NOE
;
lactose
;
oligosaccharide
Source:
Springer Online Journal Archives 1860-2000
Topics:
Biology
,
Chemistry and Pharmacology
Notes:
Abstract A theoretical full-relaxation matrix analysis of heteronuclear Overhauser effects in oligosaccharides is described. This analysis predicts that trans-glycosidic heteronuclear 1H{13C} NOEs should be measurable in a model disaccharide with appropriate enrichment with 13C and 2H. These predictions are confirmed experimentally, and the value of these measurements is discussed for conformational analysis.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1008216712371
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