ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
Each of the title compounds, 8-methoxy-7,7-bis(triphenylphosphine-P)-8,9:10,11-di-μH-7-platina-nido-undecaborane dichloromethane hemisolvate, [Pt(CH14B10O)(C18H15P)2]·0.5CH2Cl2, (I), 8-isopropoxy-7,7-bis(triphenylphosphine-P)-8,9:10,11-di-μH-7-platina-nido-undecaborane dichloromethane solvate, [Pt(C3H18B10O)(C18H15P)2]·CH2Cl2, (II), and 9-isopropoxy-7,7-bis(triphenylphosphine-P)-8,9:10,11-di-μH-7-platina-nido-undecaborane dichloromethane solvate, [Pt(C3H18B10O)(C18H15P)2]·CH2Cl2, (III), has an 11-vertex nido polyhedral skeleton, with the 7-platinum centre ligating to two exo-polyhedral PPh3 groups and an alkoxy-substituted polyhedral borane ligand. Compounds (II) and (III) are isomers. The Pt—B distances are in the range 2.214 (7)–2.303 (7) Å for (I), 2.178 (16)–2.326 (16) Å for (II) and 2.205 (6)–2.327 (6) Å for (III).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270101007788
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