ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Hitherto unknown MgPdF6 [a = 4.98, c = 13.48 Å], CaPdF6 [a = 5.19, c = 14.59 Å], ZnPdF6 [a = 4.95, c = 13.69 Å] and CdPdF6 [a = 5.08, c = 14.39 Å] have been prepared, all of the hexagonal LiSbF6-type of structure. In addition, newly prepared are Li2PdF6 [a = 10.09, b = 4.64, c = 4.63 Å; β = 117°] and Li2PtF6 [a = 10.23, b = 4.68, c = 4.65 Å; β = 117°], both of the monoclinic Na2SnF6-type of structure. It is confirmed that Na2PdF6 is isotypic with Na2SiF6. The compounds are partly yellow, partly brownish-yellow.
Notes:
Neu dargestellt wurden die hexagonalen Verbindungen MgPdF6 [a = 4,98 Å, c = 13,48 Å], CaPdF6 [a = 5,19 Å, c = 14,59 Å], ZnPdF6 [a = 4,95 Å, c = 13,69 Å] und CdPdF6 [a = 5,08 Å, c = 14,39 Å], die alle zum LiSbF6-Typ gehören und teils hellgelb, teils bräunlichgelb aussehen. Ebenfalls neu erhielt man die zum monoklinen Na2SnF6-Typ gehörenden Verbindungen Li2PdF6 [a = 10,09 Å, b = 4,64 Å, c = 4,63 Å, β = 117°] und Li2PtF6 [a = 10,23 Å, b = 4,68 Å, c = 4,65 Å, β = 117°]. Die Isotypie von Na2PdF6 mit Na2SiF6 wird bestätigt.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19683590305
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